Corrosion of carbon steels in high-temperature water studied by electrochemical techniques

Electrochemical methods were used to study the corrosion behavior of five Fe-Cr alloy steels and 304L stainless steel in high-temperature water. Passivity can be achieved on A-106 B carbon steel with a small content of chromium, which cannot be passivated at room temperature. The formation rate and the stability of the magnetite film increased with increasing Cr content in the steels. A mechanistic model was developed to describe the corrosion processes of steels in high-temperature water. The crack growth rate on steels was calculated from the maximum current of the repassivation curves according to the slip-oxidation model. There was a high crack growth rate on 304L stainless steel in high-temperature water. Of the four Fe-Cr alloys, the crack growth rate was lower on 0.236% Cr- and 0.33% Cr-steels than on 0.406% Cr steel and 2.5% Cr-1% Mo steel. The crack growth rate on 0.33% Cr steel was the smallest over the tested potential range. An increase in Cr content in the steel is predicted to reduce the corrosion rate of steel at high temperatures. However, this increase in Cr content is predicted not to reduce the susceptibility of steel to cracking at high temperatures. (C) 2004 Elsevier Ltd. All rights reserved.