Stability of semiconducting transition metal dichalcogenides irradiated by soft X-rays and low energy electrons

被引:5
作者
Walker, Roger C., II [1 ]
Bhimanapati, Ganesh R. [1 ]
Shi, Tan [2 ]
Zhang, Kehao [1 ]
Eichfeld, Sarah M. [1 ]
Jovanovic, Igor [2 ]
Robinson, Joshua A. [1 ]
机构
[1] Penn State Univ, Ctr Dimens Layered Mat 2, Dept Mat Sci & Engn, University Pk, PA 16802 USA
[2] Univ Michigan, Dept Nucl Engn & Radiol Sci, Ann Arbor, MI 48109 USA
关键词
MOLYBDENUM-DISULFIDE; RADIATION-DAMAGE; FLOOD GUN; SURFACE; SPECTROSCOPY; GRAPHENE; NITRIDE; AL2O3; OXIDE; WSE2;
D O I
10.1063/1.4982626
中图分类号
O59 [应用物理学];
学科分类号
摘要
Semiconducting two-dimensional materials (2DMs) such as molybdenum disulfide and tungsten diselenide have attracted significant attention due to their unique electronic properties. Understanding their nanoscale radiation tolerance is needed for developing radiation-hardened nanoelectronics. Here, we report that the XPS environment of soft X-ray (E = 1.486 keV) exposure in a vacuum combined with a low energy electron flood gun leads to charge accumulation in the 2D layers over time, with little impact on layer chemistry. Additionally, the charging that induced the 2DM/substrate heterostructure depends more on the growth technique, the size of as-grown domains, and the surface coverage of the 2DM than the conductivity of the substrate. Charging is minimized for the combination of a continuous 2DM film and strong coupling between the 2DM and the substrate. Published by AIP Publishing.
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页数:5
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