High molar extinction coefficient amphiphilic ruthenium sensitizers for efficient and stable mesoscopic dye-sensitized solar cells

被引:38
|
作者
Giribabu, Lingamallu [1 ]
Kumar, Challuri Vijay [1 ]
Rao, Chikkam Srinivasa [1 ]
Reddy, Veeranagari Gopal [1 ]
Reddy, Paidi Yella [1 ]
Chandrasekharam, Malapaka [1 ]
Soujanya, Yarasi [2 ]
机构
[1] Indian Inst Chem Technol, Inorgan & Phys Chem Div, Nanomat Lab, Hyderabad 500007, Andhra Pradesh, India
[2] Indian Inst Chem Technol, Mol Modelling Grp, Hyderabad 500007, Andhra Pradesh, India
关键词
ZINC PHTHALOCYANINE; LIGHT; CONVERSION; COMPLEXES;
D O I
10.1039/b903967h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two efficient heteroleptic ruthenium (II) complexes, cisdi(thiocyanato)(4,4'-dicarboxylic acid-2,2'-bipyridine)(4,4'-bis(2(3,5-di tert- butylphenyl) ethenyl)-2,2'-bipyridine)ruthenium (II) (HRD-1) and cis-di(thiocyanato)(4,4'-dicarboxylicacid-2,2'-bipyridine)(4,4'-bis(2-(2,3,5-trimethylphenyl)ethenyl)-2,2'-bipyridine) ruthenium (II) (HRD-2) were synthesized and characterized, which when anchored onto nanocrystalline TiO2 shows efficiency of 5.77 and 4.87% respectively, using durable redox electrolytes.
引用
收藏
页码:770 / 773
页数:4
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