Evaluation of rheological and mechanical behavior of blends based on polypropylene and metallocene elastomers

被引:58
作者
Da Silva, ALN
Rocha, MCG
Coutinho, FMB [1 ]
Bretas, RES
Farah, M
机构
[1] Univ Fed Rio de Janeiro, Inst Macromol Professora Eloisa Mano, IMA, Rio de Janeiro, Brazil
[2] Univ Estado Rio De Janeiro, Inst Politecn, Rio De Janeiro, Brazil
[3] Univ Estado Rio De Janeiro, IQ, Dept Proc Ind, Rio De Janeiro, Brazil
[4] Univ Fed Sao Carlos, Dept Mat Engn, Sao Carlos, SP, Brazil
关键词
polypropylene blends; metallocene elastomers; rheological behaviour; mechanical properties;
D O I
10.1016/S0142-9418(01)00137-4
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Rheological and mechanical studies were performed on polymer blends of different grades of ethylene-octene copolymers (EOCs) and polypropylene (PP). The oscillatory flow properties of EOC, PP and EOCs/PP blends were analyzed using a Rheometrics Dynamic Stress Rheometer, SR 200. The results showed that the systems with elastomers of different grades presented diversified rheological and mechanical behavior. This behavior is probably related to the differences in molecular weight and the long chain branch content present in the copolymers. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:647 / 652
页数:6
相关论文
共 13 条
[1]  
[Anonymous], 1989, POLYM ALLOYS BLENDS
[2]  
CHANG SH, 1986, J APPL POLYM SCI, V32, P6281
[3]  
Da Silva ALN, 2000, J APPL POLYM SCI, V75, P692, DOI 10.1002/(SICI)1097-4628(20000131)75:5<692::AID-APP12>3.0.CO
[4]  
2-Y
[5]   IMPACT TOUGHENING OF POLYPROPYLENE BY ETHYLENE VINYL-ACETATE COPOLYMER [J].
GUPTA, AK ;
RATNAM, BK ;
SRINIVASAN, KR .
JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 45 (07) :1303-1312
[6]  
Hornsby PR, 1998, J APPL POLYM SCI, V70, P587, DOI 10.1002/(SICI)1097-4628(19981017)70:3<587::AID-APP21>3.0.CO
[7]  
2-X
[8]  
LAI S, 1994, ANTEC 94 - PLASTICS: GATE WAY TO THE FUTURE, VOLS 1-3, P1814
[9]  
PARIKH DR, 1998, METALLOCENE CATALYSE, P113
[10]   Phase structure of ternary polypropylene/elastomer/filler composites: effect of elastomer polarity [J].
Premphet, K ;
Horanont, P .
POLYMER, 2000, 41 (26) :9283-9290