Joining of Metallic Cap and Anode-Supported Tubular Solid Oxide Fuel Cell by Induction Brazing Process

被引:2
作者
Kim, Jong-Hee [1 ]
Song, Rak-Hyun [1 ]
Shin, Dong-Ryul [1 ]
机构
[1] Korea Inst Energy Res, New Energy Res Dept, Taejon 305343, South Korea
来源
JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY | 2009年 / 6卷 / 03期
关键词
anodes; brazing; electrical conductivity; filler metals; induction heating; nickel; solid oxide fuel cells; valves; CERAMIC PLATES; FABRICATION; CONDUCTORS; DESIGN;
D O I
10.1115/1.3006344
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The anode-supported tubular solid oxide fuel cells were fabricated and joined onto the metal cap (SUS430) for current collecting and sealing by using the induction brazing process. Among five filler materials used in the induction brazing, Ni-based BNi2 has shown the lowest gas permeability of 1x10(-6) l cm(-2) s(-1) at a differential pressure of 3 atm measured with He gas. The electrical conductivity of anode support brazed with BNi2 showed 450 S cm(-1) at 750 degrees C and stable value even at the long-term and thermal cycle tests. The brazed anode-supported tubular cell at operating temperature of 750 degrees C produced 210 mW/cm(2) at 0.7 V. The gas-tightness was confirmed by open circuit voltage (OCV) value similar to theoretical value. The cell showed a stable performance and OCV for 200 h.
引用
收藏
页码:0310121 / 0310126
页数:6
相关论文
共 15 条
  • [1] Silver wire seal design for planar solid oxide fuel cell stack
    Duquette, J
    Petric, A
    [J]. JOURNAL OF POWER SOURCES, 2004, 137 (01) : 71 - 75
  • [2] A novel method to evaluate the suitability of glass sealant-alloy combinations under SOFC stack conditions
    Haanappel, VAC
    Shemet, V
    Vinke, IC
    Quadakkers, WJ
    [J]. JOURNAL OF POWER SOURCES, 2005, 141 (01) : 102 - 107
  • [3] Joining mixed conducting oxides using an air-fired electrically conductive braze
    Hardy, JS
    Kim, JY
    Weil, KS
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (08) : J43 - J49
  • [4] Cathode current-collectors for a novel tubular SOFC design
    Hatchwell, CE
    Sammes, NM
    Kendall, K
    [J]. JOURNAL OF POWER SOURCES, 1998, 70 (01) : 85 - 90
  • [5] Preparation and properties of small diameter tubular solid oxide fuel cells for rapid start-up
    Kilbride, IP
    [J]. JOURNAL OF POWER SOURCES, 1996, 61 (1-2) : 167 - 171
  • [6] Fabrication and characteristics of anode-supported flat-tube solid oxide fuel cell
    Kim, JH
    Song, RH
    Song, KS
    Hyun, SH
    Shin, DR
    Yokokawa, H
    [J]. JOURNAL OF POWER SOURCES, 2003, 122 (02) : 138 - 143
  • [7] Novel metal-ceramic joining for planar SOFCs
    Kim, JY
    Hardy, JS
    Weil, KS
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (06) : J52 - J58
  • [8] Minh N.Q., 1995, Science and Technology of Ceramic Fuel Cells, P233, DOI 10.1016/B978-044489568-4/50010-4
  • [9] Design and fabrication of a 100 W anode supported micro-tubular SOFC stack
    Sammes, NM
    Du, Y
    Bove, R
    [J]. JOURNAL OF POWER SOURCES, 2005, 145 (02) : 428 - 434
  • [10] Singhal SC, 1997, ELEC SOC S, V97, P37