Transition metals on the (0001) surface of graphite: Fundamental aspects of adsorption, diffusion, and morphology

被引:61
|
作者
Appy, David [1 ,2 ]
Lei, Huaping [1 ,3 ,5 ]
Wang, Cai-Zhuang [1 ]
Tringides, Michael C. [1 ,3 ]
Liu, Da-Jiang [1 ]
Evans, James W. [1 ,3 ]
Thiel, Patricia A. [1 ,2 ,4 ]
机构
[1] Ames Lab, Ames, IA 50011 USA
[2] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
[3] Iowa State Univ, Dept Phys & Astron, Ames, IA 50011 USA
[4] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA
[5] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
基金
美国国家科学基金会;
关键词
Graphite; Graphene; Transition metal; Nucleation; Adsorption; Diffusion; SCANNING-TUNNELING-MICROSCOPY; ORIENTED PYROLYTIC-GRAPHITE; GOLD CLUSTERS; NANOPARTICLE ARRAYS; ATOMIC-RESOLUTION; EQUILIBRIUM SHAPE; MOLECULE CORRALS; DENDRITIC GROWTH; AU PARTICLES; SUBSTRATE;
D O I
10.1016/j.progsurf.2014.08.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this article, we review basic information about the interaction of transition metal atoms with the (0001) surface of graphite, especially fundamental phenomena related to growth. Those phenomena involve adatom-surface bonding, diffusion, morphology of metal clusters, interactions with steps and sputter-induced defects, condensation, and desorption. General traits emerge which have not been summarized previously. Some of these features are rather surprising when compared with metal-on-metal adsorption and growth. Opportunities for future work are pointed out. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:219 / 238
页数:20
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