Phase cooperation of V2O5 and Bi2O3 in the selective oxidation of H2S containing ammonia and water

被引：17

作者：

Cho, YG ^{[1
]}

Hwang, BH ^{[1
]}

Park, DW ^{[1
]}

Woo, HC ^{[1
]}

Chung, JS ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Chem Engn, Pusan 609735, South Korea

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2002年 / 19卷 / 04期

关键词：

hydrogen sulfide; selective oxidation; phase cooperation; vanadium oxide; bismuth oxide;

D O I：

10.1007/BF02699305

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The selective oxidation of hydrogen sulfide containing excess water and ammonia was studied over vanadium oxide-based catalysts. The investigation was focused on the role of V2O5, and phase cooperation between V2O5 and Bi2O3 in this reaction. The conversion of H2S continued to decrease since V2O5 was gradually reduced by treatment with H2S. The activity of V2O5 was recovered by contact with oxygen. A strong synergistic phenomenon in catalytic activity was observed for the mechanically mixed catalysts of V2O5 and Bi2O3. Temperature-programmed reduction (TPR) and oxidation (TPO) and two bed reaction tests were performed to explain this synergistic effect by the reoxidation ability of Bi2O3.

引用

页码：611 / 616

页数：6

共 20 条

[1] Berben P., 1987, Stud. Surf. Sci. Catal., V34, P303
[2] Selective oxidation of H2S in the presence of ammonia and water using Co3O4/SiO2 catalyst
Chun, SW
Jang, JY
Park, DW
Woo, HC
Chung, JS
[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 1997, 14 (03) : 216 - 218
[3] CHUN SW, 1988, APPL CATAL B-ENVIRON, V16, P235
[4] CHUN SW, 1998, THESIS PUSAN NATL U
[5] HAAS RH, 1985, Patent No. 4528277
[6] KETTNER R, 1983, Patent No. 0078690
[7] KETTNER R, 1988, OIL GAS J 0111, P63
[8] Synthesis of maleic and phthalic anhydrides from the mixture of cyclopentene and 1-pentene
Kim, YH
Yang, HS
[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2000, 17 (03) : 357 - 364
[9] LAGAS JA, 1988, OIL GAS J, V86, P68
[10] LELL R, 1985, SULPHUR, V178, P29

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