Effect of montmorillonite on the properties of thermosensitive poly(N-isopropylacrylamide) composite hydrogels

Thermosensitive composite hydrogels containing various amounts of sodium montmorillonite (NaMM) and poly(N-isopropylacrylamide) (pNIPAAm) were synthesized. Their equilibrium degree of swelling (DS) was measured in NaCl solutions of different ionic strength and at various temperatures. The DS decreased when increasing the clay content and no Substantial shift in the phase transition temperature was noticed. The composite hydrogels investigated had a NaMM content ranging between 1.0 and 5.7 wt% (in 0.1M NaCl at 25degreesC). A considerable enhancement in the response to thermal stimuli was observed for NaMM contents >2-3 wt% It is suggested that when the NaMM concentration approaches a critical value, the clay platelets can inhibit the formation of the hydrophobic skin layer that hinders shrinking in conventional pNIPAAm hydrogels. The effect of montmorillonite on the mechanical properties of the hydrogels was investigated by uniaxial compression tests, which showed that the modulus increases with the NaMM content. (C) 2004 Wiley Periodicals, Inc.