Synthesis of cyclic carbonates from epoxides catalyzed by metal-BINOL complexes

被引：8

作者：

Bai, Dongsheng ^{[1
]}

Wang, Guangjian ^{[1
]}

Ma, Fang ^{[1
]}

Wang, Juangang ^{[1
]}

Wang, Kuai ^{[1
]}

Yang, Zijing ^{[1
]}

机构：

[1] Huaibei Normal Univ, Coll Chem & Mat Sci, Huaibei 235000, Anhui, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2014年 / 28卷 / 11期

关键词：

cycloaddition; epoxides; carbon dioxide; cyclic carbonate; BINOL; CHEMICAL FIXATION; IONIC LIQUIDS; EFFICIENT CATALYST; CO2; FIXATION; DIOXIDE; CYCLOADDITION; COPOLYMERIZATION; CARBENES; SYSTEM; ZN;

D O I：

10.1002/aoc.3204

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Synthesis of cyclic carbonates from CO2 and terminal epoxides catalyzed by Mg, Ca and In BINOL complexes was achieved without organic solvents. Effects of temperature, CO2 pressure, reaction time and co-catalyst on the cycloaddition were investigated. Propylene carbonate was obtained under a CO2 pressure of 1.2 MPa within 10 hours in a yield of 98% catalyzed by Ca-BINOL at 120 degrees C. The order of catalytic activity of the metal center is Ca>In>Mg. Copyright (c) 2014 John Wiley & Sons, Ltd.

引用

页码：814 / 817

页数：4

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