Influence of inorganic ions and selected emerging contaminants on the degradation of Methylparaben: A sonochemical approach

被引:63
作者
Sasi, Subha [1 ]
Rayaroth, Manoi P. [2 ]
Devadasan, Dineep [3 ]
Aravind, Usha K. [1 ,4 ]
Aravindakumar, Charuvila T. [2 ,3 ]
机构
[1] Mahatma Gandhi Univ, Adv Ctr Environm Studies & Sustainable Dev, Kottayam 686560, Kerala, India
[2] Mahatma Gandhi Univ, Sch Environm Sci, Kottayam 686560, Kerala, India
[3] Mahatma Gandhi Univ, Inter Univ Instrumentat Ctr, Kottayam 686560, Kerala, India
[4] Kiranam, Ctr Environm Educ & Technol, Kottayam 686008, Kerala, India
关键词
Emerging pollutants; Parabens; Sonolysis; LC-Q-TOF-MS analysis; Mineralization; PHTHALIC-ACID ESTERS; WASTE-WATER; AQUEOUS-SOLUTIONS; TREATMENT PLANTS; PARABENS; HYDROLYSIS; OXIDATION; SONOLYSIS; KINETICS; MECHANISM;
D O I
10.1016/j.jhazmat.2015.06.072
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The study on the possible pathway of hydroxyl radicals mediated sonolytic degradation of paraben in water is reported. Methylparaben (MPB) which is the most utilized of paraben family is selected as a model emerging pollutant. The influence of common anions and some selected emerging contaminants that may coexist in typical water matrix on the degradation pattern is analyzed alongside. Among the anions, carbonate presents a negative influence which is attributed to the competition for OH radical. Some emerging contaminants also showed negative impact on degradation as was clear from HPLC data. The intermediates, analyzed by LC-Q-TOF-MS include hydroxylated and hydrolytic products. Three major steps (aromatic hydroxylation, hydroxylation at the ester chain and hydrolysis) are proposed to involve in the reaction of OH radical with MPB which ultimately leads to mineralization. The intensity of formation and decay of mono and dihydroxy products of MPB in the presence of additives have also been evaluated. COD analysis indicates a percentage reduction of 98% at 90 min of sonolysis and further increase in the degradation time resulted complete mineralization, which became evident from the mass spectrometric data. MIT assay revealed considerable decrease in the potential cytotoxicity. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:202 / 209
页数:8
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