Stimulus-Responsive Metal-Organic Frameworks

被引：117

作者：

Nagarkar, Sanjog S. ^{[1
]}

Desai, Aamod V. ^{[1
]}

Ghosh, Sujit K. ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res, Dept Chem, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2014年 / 9卷 / 09期

关键词：

adsorption; host-guest systems; metal-organic frameworks; polymers; stimulus response; POROUS COORDINATION POLYMERS; PROTON CONDUCTION; POSTSYNTHETIC LIGAND; CO2; ADSORPTION; SPIN-CROSSOVER; PORE-SIZE; BEHAVIOR; TEMPERATURE; PRESSURE; EXCHANGE;

D O I：

10.1002/asia.201402004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Materials that can recognize the changes in their local environment and respond by altering their inherent physical and/or chemical properties are strong candidates for future "smart" technology materials. Metal-organic frameworks (MOFs)have attracted a great deal of attention in recent years owing to their designable architecture, host-guest chemistry, and softness as porous materials. Despite this fact, studies on the tuning of the properties of MOFs by external stimuli are still rare. This review highlights the recent developments in the field of stimulus-responsive MOFs or so-called smart MOFs. In particular, the various stimuli used and the utility of stimulus-responsive smart MOFs for various applications such as gas storage and separation, sensing, clean energy, catalysis, molecular motors, and biomedical applications are highlighted by using representative examples. Future directions in the developments of stimulus-responsive smart MOFs and their applications are proposed from a personal perspective.

引用

页码：2358 / 2376

页数：19

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