Characterization of intermolecular interaction between two substances when one substance does not possess any characteristic peak

被引：19

作者：

Li, Xiaopei ^{[1
,2
,3
]}

Fan, Xiaokun ^{[1
,4
]}

Huang, Kun ^{[1
]}

Liu, Huizhou ^{[1
]}

Zhao, Ying ^{[5
]}

Wei, Yongju ^{[4
]}

Liu, Cuige ^{[4
]}

Xu, Yizhuang ^{[2
]}

Noda, Isao ^{[6
]}

Wu, Jinguang ^{[2
]}

机构：

[1] Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China

[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[4] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050024, Peoples R China

[5] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China

[6] Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1069卷

基金：

中国国家自然科学基金;

关键词：

Two-dimensional asynchronous spectroscopy; Intermolecular interaction; Asynchronous; 2-DIMENSIONAL CORRELATION SPECTROSCOPY; SAMPLE DESIGN SCHEME; INFRARED CORRELATION; IONIC-LIQUID; METAL-IONS; BEHAVIOR; COORDINATION; COMPLEXES; MECHANISM; CONJUNCTION;

D O I：

10.1016/j.molstruc.2014.01.046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We explore whether it is possible to use 2D correlation spectrum to characterize intermolecular interactions between two solutes dissolved in the same solution when one substance does not possesses any characteristic peak. We demonstrate that the interaction can be manifested by characteristic cross peaks in 2D asynchronous correlated spectrum. The above cross peaks reflect the subtle spectral variations on the characteristic peak of another solute under intermolecular interaction. On the other hand, 2D synchronous spectrum is not suitable to characterize intermolecular interaction since the cross peaks contain irremovable interfering parts. The terbium-chloride/benzamide/methanol system is used to demonstrate that this approach is applicable in the real chemical system. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：127 / 132

页数：6

共 44 条

[1] Intramolecular carbohydrate-aromatic interactions and intermolecular van der Waals interactions enhance the molecular recognition ability of GMI glycomimetics for cholera toxin [J].

Bernardi, A ;

Arosio, D ;

Potenza, D ;

Sánchez-Medina, I ;

Mari, S ;

Cañada, FJ ;

Jiménez-Barbero, J .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (18) :4395-4406

[2] Double Asynchronous Orthogonal Sample Design Scheme for Probing Intermolecular Interactions [J].

Chen, Jing ;

Bi, Quan ;

Liu, Shaoxuan ;

Li, Xiaopei ;

Liu, Yuhai ;

Zhai, Yanjun ;

Zhao, Ying ;

Yang, Limin ;

Xu, Yizhuang ;

Noda, Isao ;

Wu, Jinguang .

JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 116 (45) :10904-10916

[3] Two-Dimensional Infrared Correlation Spectroscopy and Principal Component Analysis on the Carbonation of Sterically Hindered Alkanolamines [J].

Cheon, Youngeun ;

Jung, Young Mee ;

Lee, Jeesun ;

Kim, Heehwan ;

Im, Jinkyu ;

Cheong, Minserk ;

Kim, Hoon Sik ;

Park, Ho Seok .

CHEMPHYSCHEM, 2012, 13 (14) :3365-3369

[4] Functionally Important Aromatic-Aromatic and Sulfur-π Interactions in the D2 Dopamine Receptor [J].

Daeffler, Kristina N. -M. ;

Lester, Henry A. ;

Dougherty, Dennis A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (36) :14890-14896

[5] A femtosecond study of excitation wavelength dependence of a triblock copolymer -: Surfactant supramolecular assembly:: (PEO)20-(PPO)70-(PEO)20 and CTAC [J].

Dey, Shantanu ;

Adhikari, Aniruddha ;

Mandal, Ujjwal ;

Ghosh, Subhadip ;

Bhattacharyya, Kankan .

JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (16) :5020-5026

[6] Supramolecular assembly of 2,4,5-trifluorobenzoate complex based on weak interactions involving fluorine atoms [J].

Ge, Chun-Hua ;

Zhang, Rui ;

Fan, Ping ;

Zhang, Xiang-Dong ;

Wang, Li-Juan ;

Wang, Fang-Fang .

CHINESE CHEMICAL LETTERS, 2013, 24 (01) :73-75

[7] Investigation on the Melt Spinning Fibers of PP/Organoclay Nanocomposites Prepared by In-Situ Polymerization [J].

Hao, Chaowei ;

Zhao, Ying ;

He, Aihua ;

Zhang, Xiuqin ;

Wang, Dujin ;

Ma, Qingfang ;

Xu, Yizhuang .

JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (03) :1384-1391

[8] Anomalous rheological behavior of poly(1-vinyl-2-pyrrolidone) and CuCl2 in solution and their interactions in solid composites [J].

Hao, Chaowei ;

Zhao, Ying ;

Dong, Xia ;

Zhou, Yong ;

Xu, Yizhuang ;

Wang, Dujin ;

Lai, Guoqiao ;

Jiang, Jianxiong .

POLYMER INTERNATIONAL, 2009, 58 (08) :906-911

[9] The Hydrogen-Bonding Interactions between 1-Ethyl-3-Methylimidazolium Lactate Ionic Liquid and Methanol [J].

He, Hongyan ;

Chen, Hui ;

Zheng, Yanzhen ;

Zhang, Xiaochun ;

Yao, Xiaoqian ;

Yu, Zhiwu ;

Zhang, Suojiang .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2013, 66 (01) :50-59

[10] Preparation and spectroscopic characterization of two HoCl3-galactitol complexes and one ErCl3-galactitol complex [J].

Hua, Xiaohui ;

Pan, Qinghua ;

Yu, Lei ;

Xue, Junhui ;

Yang, Limin ;

Xu, Yizhuang ;

Zhao, Guozhong ;

Li, Weihong ;

Wang, Zheming ;

Wu, Jinguang ;

Liu, Kexin ;

Chen, Jia'er .

JOURNAL OF MOLECULAR STRUCTURE, 2011, 998 (1-3) :225-232

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