One-Pot Synthesis of MoS2 Flowers Grown On Prussian Blue Cubes For the Sensitive Detection of Catechol In Water Samples

被引:0
作者
Keerthi, Murugan [1 ]
Renganathan, Vengudusamy [1 ]
Chen, Shen-Ming [1 ]
Chen, Tse-Wei [1 ]
机构
[1] Natl Taipei Univ Technol, Dept Chem Engn & Biotechnol, Taipei 106, Taiwan
来源
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2018年 / 13卷 / 02期
关键词
Prussian blue cubes; MoS2; flowers; catechol; water pollutant; organic toxic; GRAPHENE-OXIDE; ELECTRODE MATERIAL; COMPOSITE; HYDROQUINONE; CO;
D O I
10.20964/2018.02.51
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Herein, we reported a robust electrochemical sensor to detect catechol, developed through the one-pot synthesis of MoS2 flowers grown on Prussian Blue Cubes. Recently, numerous articles reported about the issue that the water resources were polluted excessively by the chemical and organic toxins. It is a significant concern that the level of toxic compounds exceeds the limits in drinking. Therefore, it is crucial to develop a sensitive, reproducible and long-lasting sensor for the real-time detection of catechol. Thus, we have generated an electrochemical sensor through the economic screen-printed carbon electrode (SPCE) modification method. PB/MoS2 are economically fabricated on the carbon film of SPCE. As a result, the modified electrode showed exceptional electrocatalytic ability towards catechol, and the redox peak current is associated with the concentrations of catechol. It holds more extensive working range between 25 nM and 1265 mu M, and it possesses a very low limit of detection as well as the appreciable sensitivity. This method is successfully applied to the detection of catechol in drinking and river water samples.
引用
收藏
页码:1568 / 1576
页数:9
相关论文
共 32 条
  • [1] Akilarasan M., 2017, INT J ELECTROCHEM SC, V12, P7446
  • [2] [Anonymous], MICROCHIMICA ACTA
  • [3] The effect of acetic acid on the photocatalytic degradation of catechol and resorcinol
    Araña, J
    Rodríguez, JMD
    Díaz, OG
    Melián, JAH
    Rodríguez, CF
    Peña, JP
    [J]. APPLIED CATALYSIS A-GENERAL, 2006, 299 (1-2) : 274 - 284
  • [4] DIFFUSION-CONTROLLED REACTION RATES
    COLLINS, FC
    KIMBALL, GE
    [J]. JOURNAL OF COLLOID SCIENCE, 1949, 4 (04): : 425 - 437
  • [5] Catalysis of catechol oxidation by metal-dithiocarbamate complexes in pesticides
    Fitsanakis, VA
    Amarnath, V
    Moore, JT
    Montine, KS
    Zhang, J
    Montine, TJ
    [J]. FREE RADICAL BIOLOGY AND MEDICINE, 2002, 33 (12) : 1714 - 1723
  • [6] FOX P, 1988, J WATER POLLUT CON F, V60, P86
  • [7] SMALL-SIGNAL AC RESPONSE THEORY FOR ELECTROCHROMIC THIN-FILMS
    FRANCESCHETTI, DR
    MACDONALD, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (08) : 1754 - 1756
  • [8] CHANGES OF ELECTRONIC STATES OF A MIXED-VALENCE COMPOUND AT HIGH-PRESSURES - INSOLUBLE PRUSSIAN BLUE, FE4[FE(CN)6]3
    HARA, Y
    MINOMURA, S
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (12) : 5339 - 5343
  • [9] Itava K., 1986, ACCOUNTS CHEM RES, V19, P162
  • [10] SINGLE-LAYER MOS2
    JOENSEN, P
    FRINDT, RF
    MORRISON, SR
    [J]. MATERIALS RESEARCH BULLETIN, 1986, 21 (04) : 457 - 461