Iridium-catalyzed N-alkylation of diamines with glycerol

被引：16

作者：

Crotti, Corrado ^{[1
]}

Farnetti, Erica ^{[2
]}

Licen, Sabina ^{[2
]}

Barbieri, Pierluigi ^{[2
]}

Pitacco, Giuliana ^{[2
]}

机构：

[1] CNR, Ist Struttura Mat, Unita Operat Supporto Trieste, I-34149 Trieste, Italy

[2] Univ Trieste, Dipartimento Sci Chim & Farmaceut, I-34127 Trieste, Italy

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2014年 / 382卷

关键词：

Glycerol valorization; Iridium catalyst; Hydrogen transfer reaction (HTR); Hydrogen borrowing; Amine alkylation with glycerol; ALCOHOLS; REDUCTION; AMINES; COMPLEXES;

D O I：

10.1016/j.molcata.2013.10.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

N-alkylation of 1,2-diaminocyclohexanes with glycerol in water, catalyzed by [Cp*IrCl2](2), gives a mixture of 2-methyldecahydroquinoxaline and 2-(1-hydroxyethyl)-3a,4,5,6,7,7a-hexahydro-1H-benzimidazoles. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：64 / 70

页数：7

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