Sintered lead-free Bi-0.5(Na0.8K0.2)(0.5)(Ti(0.96)Sn(0.0)4)O-3 ceramics (BNKTS) have been fabricated via a solid-state reaction. The effect of sintering temperature on the structural, morphological, dielectric, ferroelectric and energy storage properties of BNKTS ceramics was investigated, and it was found that the electrical properties of the synthesized ceramics increased with the increase in the sintering temperature, and the highest values were achieved at 1100 degrees C. The ceramics sintered at the optimized temperature of 1100 degrees C exhibited the best physical, dielectric, ferroelectric and energy storage properties, namely, high density (the relative density, rho = 5.88 g.cm(-3), approximate to 96.7% of the theoretical value), high densification factor (DF = 0.93), high dielectric constant (epsilon(r) = 1215), low dielectric loss (tan delta = 0.051), highest dielectric constant (epsilon(max) = 4335), high remanent polarization (P-r = 9.5 mu C. cm(-2)), high coercive field (E-c = 14.3 kV/cm), high energy storage density (0.12 J/cm(3)), and high energy storage efficiency (41.7% at 46.3 kV/cm).