Metal Free Sulfonic Acid Functionalized Carbon Catalyst for Green and Mechanochemical Synthesis of Perimidines

被引:21
作者
Sahiba, Nusrat [1 ]
Sethiya, Ayushi [1 ]
Soni, Jay [1 ]
Agarwal, Shikha [1 ]
机构
[1] MLSU, Dept Chem, Synthet Organ Chem Lab, Udaipur 313001, Raj, India
来源
CHEMISTRYSELECT | 2020年 / 5卷 / 42期
关键词
Solid acid catalysis; Click chemistry; Grindstone method; Green chemistry; Nitrogen heterocycles; Perimidine; EFFICIENT CATALYST; DERIVATIVES; COMPLEXES;
D O I
10.1002/slct.202003308
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new and scalable mechanochemical approach has been developed for the synthesis of perimidine derivatives using an efficient and recyclable catalyst, carbon sulfonic acid under metal-free conditions. A wide variety of aldehydes displayed cyclo-condensation reaction with 1,8-diaminonaphthalene in EtOH under ambient reaction conditions via grind-stone technique to produce substituted perimidines in excellent yields (95-99 %) in a very short reaction time. This method has interesting features like single-step synthesis, high functional group tolerance, transition-metal free synthesis, high atom-economy, recyclable catalyst, no need of tedious purification process, gram-scale synthesis, high green chemistry matrix (Eco-score and E-factor) that make this protocol green and eco-friendly.
引用
收藏
页码:13076 / 13080
页数:5
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