Metal Free Sulfonic Acid Functionalized Carbon Catalyst for Green and Mechanochemical Synthesis of Perimidines

被引：23

作者：

Sahiba, Nusrat ^{[1
]}

Sethiya, Ayushi ^{[1
]}

Soni, Jay ^{[1
]}

Agarwal, Shikha ^{[1
]}

机构：

[1] MLSU, Dept Chem, Synthet Organ Chem Lab, Udaipur 313001, Raj, India

来源：

CHEMISTRYSELECT | 2020年 / 5卷 / 42期

关键词：

Solid acid catalysis; Click chemistry; Grindstone method; Green chemistry; Nitrogen heterocycles; Perimidine; EFFICIENT CATALYST; DERIVATIVES; COMPLEXES;

D O I：

10.1002/slct.202003308

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new and scalable mechanochemical approach has been developed for the synthesis of perimidine derivatives using an efficient and recyclable catalyst, carbon sulfonic acid under metal-free conditions. A wide variety of aldehydes displayed cyclo-condensation reaction with 1,8-diaminonaphthalene in EtOH under ambient reaction conditions via grind-stone technique to produce substituted perimidines in excellent yields (95-99 %) in a very short reaction time. This method has interesting features like single-step synthesis, high functional group tolerance, transition-metal free synthesis, high atom-economy, recyclable catalyst, no need of tedious purification process, gram-scale synthesis, high green chemistry matrix (Eco-score and E-factor) that make this protocol green and eco-friendly.

引用

页码：13076 / 13080

页数：5

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