Characteristic Features of the Sorption-Desorption of Hydrogen by Mg-M-Ni (M = Al, Mn, Ti) Ternary Alloys

被引：9

作者：

Berezovets', V. V. ^{[1
]}

Denys, R. V. ^{[1
]}

Zavalii, I. Yu ^{[1
]}

Paul-Boncour, V. ^{[2
]}

Pecharsky, V. ^{[3
]}

机构：

[1] Ukrainian Natl Acad Sci, Karpenko Physicomech Inst, Lvov, Ukraine

[2] CNRS, Inst Chim & Mat Paris Est, Thiais, France

[3] Iowa State Univ, Ames Lab, Ames, IA USA

来源：

MATERIALS SCIENCE | 2013年 / 49卷 / 02期

关键词：

hydrogen; magnesium compounds; magnesium alloys; hydrides; HYDRIDE; SYSTEM; MG2FEH6; STORAGE;

D O I：

10.1007/s11003-013-9595-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

By the method of high-energy milling in a ball mill, we obtain new alloys of Mg-M-Ni (M = Al, Mn, Ti) ternary systems. The properties of hydrogen sorption of the Mg3AlNi2 compound (Ti2Ni-type structure) are investigated and compared with the properties of Mg3MNi2 (M = Mn, Ti) isostructural compounds. The sorption-desorption of hydrogen by Mg(88)M4Ni(8) (M = Al, Mn, Ti) alloys is studied. The catalytic influence of Mg3MNi2 ternary phases on the hydrogenation of magnesium is established.

引用

页码：159 / 169

页数：11

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