Solvothermal synthesis and crystal structure of [H2N(CH2)2NH3]{CO[H2N(CH2)2NH2]3}[SbSe4]

被引：0
作者：
Ming-Lai, F
Chen, WT
Cai, LZ
Liu, B
Guo, GC [1 ]
Huang, JS
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 23卷 / 07期
关键词：
solvothermal; selenoantimonate; crystal structure; cobalt;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new molecular metal chalcogenoantimonate, 2-aminoethylammonium tris(1, 2-ethylenediamine)cobalt tetraselenoantimonate, [enH][Co(en)(3)][SbSe4] (en = ethylenediamine), has been synthesized by solvothermal reaction in an ethylenediamine/methanol solution at 443 K and structurally characterized by X-ray crystallography. The crystal belongs to triclinic, space group P (1) over bar with a = 8.900(4), b = 9.663(5), c = 14.361(6) Angstrom, alpha = 104.783(18), beta = 92.4220(10), gamma = 109.9920(10)degrees, C8H33CoN8SbSe4, M-r = 737.94, V = 1110.7(10) Angstrom(3), Z = 2, D-c = 2.207 g/cm(3), F(000) = 702, mu = 8.525 mm(-1), R = 0.0648, wR = 0.0755 and S = 1.005. The structure contains tetrahedral [SbSe4](3-) anion and octahedral [Co(en)(3)](2+) cation, as well as the monoprotonated ethylenediamine cation [enH](+).
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页码：731 / 734
页数：4
相关论文
共 19 条
[1]   Solvothermal synthesis of [Mn(en)(3)](2)[Mn-4(en)(9)(SbSe4)(4)]center dot 2H2O: the first example of a selenoantimonate(v) acting as a ligand in a transition-metal complex [J].
Bensch, W ;
Nather, C ;
Schur, M .
CHEMICAL COMMUNICATIONS, 1997, (18) :1773-1774
[2]   Novel sandwiched intermetallic selenoantimonates:: Soft synthesis and characterization of Cu2SbSe3•0.5en and Cu2SbSe3•en [J].
Chen, Z ;
Dilks, RE ;
Wang, RJ ;
Lu, JY ;
Li, J .
CHEMISTRY OF MATERIALS, 1998, 10 (10) :3184-3188
[3]   Molecular building blocks for solid-state chalcogenides:: solvothermal synthesis of [Mn(en)3]Te4 and [Fe(en)3]2(Sb2Se5) [J].
Chen, Z ;
Wang, RJ ;
Huang, XY ;
Li, J .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 (09) :1100-1103
[4]   2-aminoethylammonium tris(1,2-ethylenediamine)nickel(II) tetraselenoantimonate(V) [J].
Fu, ML ;
Chen, WT ;
Cai, LZ ;
Zhou, GW ;
Guo, GC ;
Mao, JG ;
Huang, JS .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 :M367-M369
[5]  
Girard MR, 1998, MAIN GROUP MET CHEM, V21, P231
[6]   PREPARATION AND CRYSTAL-STRUCTURE OF BA(EN)4(SBSE2)2 [J].
KONIG, T ;
EISENMANN, B ;
SCHAFER, H .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 488 (05) :126-132
[7]  
KONIG T, 1984, REV CHIM MINER, V21, P640
[8]   Synthesis and characterization of two group 15 selenometalates: [NEt(4)][BiSe2] and [Ge(en)(3)][enH][SbSe4] [J].
Pell, MA ;
Ibers, JA .
INORGANIC CHEMISTRY, 1996, 35 (16) :4559-4562
[9]  
Rigaku, 2002, CRYSTALCLEAR VERSION
[10]  
SAITOY, 1979, INORGANIC MOL DISSYM, P56
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