Recent Advances in the Selective Oxidation of Alkyl C-H Bonds Catalyzed by Iron Coordination Complexes

被引：19

作者：

Canta, Merce ^{[1
,2
]}

Rodriguez, Monica ^{[1
,2
]}

Costas, Miquel ^{[1
,2
]}

机构：

[1] Univ Girona, Fac Ciencies, Dept Quim, Campus Montilivi, Girona 17071, Catalonia, Spain

[2] Univ Girona, Fac Ciencies, Inst Quim Computac & Catalisi, Campus Montilivi, Girona 17071, Catalonia, Spain

来源：

SITE-SELECTIVE CATALYSIS | 2016年 / 372卷

关键词：

Alkyl C-H oxidation; Aminopyridine ligands; Bioinspired catalysis; Hydrogen peroxide; Iron coordination complexes; Nonheme oxygenases; Selectivity; STEREOSPECIFIC ALKANE HYDROXYLATION; 2-HIS-1-CARBOXYLATE FACIAL TRIAD; NAPHTHALENE DIOXYGENASE; ACTIVATION; OXO; FUNCTIONALIZATION; MECHANISM; OXYGENATION; PLATFORM; LIGANDS;

D O I：

10.1007/128_2015_659

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selective and stereoretentive oxidation of alkyl C-H bonds has been described over the last decade by employing biologically inspired iron coordination complexes as catalysts and hydrogen peroxide as oxidant. Examples of catalyst dependent C-H site selectivity have started to appear. The current paper describes an account of these findings.

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页码：27 / 54

页数：28

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