Recent Advances in the Selective Oxidation of Alkyl C-H Bonds Catalyzed by Iron Coordination Complexes

被引：19
|
作者：
Canta, Merce [1 ,2 ]
Rodriguez, Monica [1 ,2 ]
Costas, Miquel [1 ,2 ]
机构：
[1] Univ Girona, Fac Ciencies, Dept Quim, Campus Montilivi, Girona 17071, Catalonia, Spain
[2] Univ Girona, Fac Ciencies, Inst Quim Computac & Catalisi, Campus Montilivi, Girona 17071, Catalonia, Spain
来源：
SITE-SELECTIVE CATALYSIS | 2016年 / 372卷
关键词：
Alkyl C-H oxidation; Aminopyridine ligands; Bioinspired catalysis; Hydrogen peroxide; Iron coordination complexes; Nonheme oxygenases; Selectivity; STEREOSPECIFIC ALKANE HYDROXYLATION; 2-HIS-1-CARBOXYLATE FACIAL TRIAD; NAPHTHALENE DIOXYGENASE; ACTIVATION; OXO; FUNCTIONALIZATION; MECHANISM; OXYGENATION; PLATFORM; LIGANDS;
D O I：
10.1007/128_2015_659
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Selective and stereoretentive oxidation of alkyl C-H bonds has been described over the last decade by employing biologically inspired iron coordination complexes as catalysts and hydrogen peroxide as oxidant. Examples of catalyst dependent C-H site selectivity have started to appear. The current paper describes an account of these findings.
引用
收藏
页码：27 / 54
页数：28
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