Tetraphenylethylene-based phosphine: tuneable emission and carbon dioxide fixation

被引:28
作者
Zhang, Jianyong [1 ]
Yang, Qiuti [1 ]
Zhu, Yixuan [1 ]
Liu, Haoliang [1 ]
Chi, Zhenguo [1 ]
Su, Cheng-Yong [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, KLGHEI Environm & Energy Chem, MOE Key Lab Polymer Composite & Funct Mat, Guangzhou 510275, Guangdong, Peoples R China
关键词
METAL-ORGANIC FRAMEWORKS; AGGREGATION-INDUCED EMISSION; TURN-ON FLUORESCENCE; ATMOSPHERIC CO2 FIXATION; FUNCTIONALIZED TETRAPHENYLETHENE; COPPER(II) COMPLEXES; ENHANCED EMISSION; CLUSTERS; BINDING; LIGANDS;
D O I
10.1039/c4dt01808g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A tetraphenylethylene-based phosphine, 1,1,2,2-tetrakis((4-diphenyiphosphino)phenypethylene (TPE-P4), was synthesized and showed novel aggregation-induced and mechano-responsive emission. A mixture of TPE-P4 and Ag+ could fix atmospheric CO2 in situ as carbonate ions in neutral solution to yield a rare 3D metal-organic framework with zeolite-like SOD topology, [Ag-2(TPE-P-4)CO3](x), superset of nH(2)O (Ag-TPE-P4). Ag-TPE-P4 showed turn-on luminescence of TPE-P4, emitting bright bluish green light in the solid state.
引用
收藏
页码:15785 / 15790
页数:6
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