Organometallic coordination networks based on π-bonded transition metal quinonoid complexes

被引：0
|
作者：
Reingold, Jeffrey A.
Son, Seung Uk
Carpenter, Gene B.
Sweigart, Dwight A. [1 ]
机构：
[1] Brown Univ, Dept Chem, Providence, RI 02912 USA
[2] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
来源：
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2006年 / 16卷 / 01期
基金：
美国国家科学基金会;
关键词：
coordination networks; hydrogen-bonding; quinone complexes; organometalloligand; polymers; self-assembly;
D O I：
10.1007/s10904-006-9024-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Hydroquinones pi-bonded to the transition metal fragments Mn(CO)(3)(+), Rh(COD)(+), and Rh [P(OPh)(3)](2)(+) are readily deprotonated to afford anionic eta(4)-quinone complexes that function as organometalloligands by binding to metal ions through the quinone oxygen atoms. The resulting supramolecular assemblies display a variety of interesting and potentially useful network topologies.
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页码：1 / 13
页数：13
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