Organometallic coordination networks based on π-bonded transition metal quinonoid complexes

被引：0

作者：

Reingold, Jeffrey A.

Son, Seung Uk

Carpenter, Gene B.

Sweigart, Dwight A. ^{[1
]}

机构：

[1] Brown Univ, Dept Chem, Providence, RI 02912 USA

[2] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2006年 / 16卷 / 01期

基金：

美国国家科学基金会;

关键词：

coordination networks; hydrogen-bonding; quinone complexes; organometalloligand; polymers; self-assembly;

D O I：

10.1007/s10904-006-9024-0

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hydroquinones pi-bonded to the transition metal fragments Mn(CO)(3)(+), Rh(COD)(+), and Rh [P(OPh)(3)](2)(+) are readily deprotonated to afford anionic eta(4)-quinone complexes that function as organometalloligands by binding to metal ions through the quinone oxygen atoms. The resulting supramolecular assemblies display a variety of interesting and potentially useful network topologies.

引用

页码：1 / 13

页数：13

共 54 条

[1] Co-ordination polymers containing square grids of dimension 15 x 15 Å [J].