Synthesis of Ruthenium Complex Based on 2,6-Bis(1-(phenyl)-1H-benzo[d] imidazol-2-yl) pyridine and 2-(1-Phenyl-1H-benzo[d]imidazol-2-yl)benzoate and Catalytical Oxidation Property of 1-(1H-Benzo[d]imidazol-2-yl) ethanol to 1-(1H-Benzo[d]imidazol-2-yl) ethanone with H2O2

被引：23
|
作者：
Liu, Shenggui [1 ]
Pan, Rongkai [1 ]
Li, Guobi [1 ]
Su, Wenyi [1 ]
Ni, Chunlin [2 ]
机构：
[1] Lingnan Normal Univ, Sch Chem & Chem Engn, Zhanjiang 524048, Peoples R China
[2] South China Agr Univ, Coll Mat & Energy, Guangzhou 510642, Guangdong, Peoples R China
来源：
JOURNAL OF CHEMISTRY | 2017年 / 2017卷
关键词：
HYDROGEN-PEROXIDE; BENZIMIDAZOLE DERIVATIVES; SELECTIVE OXIDATION; CRYSTAL-STRUCTURE; ALCOHOLS; EPOXIDATION;
D O I：
10.1155/2017/8647419
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new ruthenium complex, Ru(bpbp)(pbb) Cl, based on 2,6-bis(1-(phenyl)-1H-benzo[d] imidazol-2-yl) pyridine (bpbp) and 2-(1phenyl- 1H-benzo[d] imidazol-2-yl) benzoate (pbb) was synthesized. The complex Ru(bpbp)(pbb) Cl could catalytically oxidize 1(1H-benzo[d] imidazol-2-yl) ethanol to 1-(1H-benzo[d] imidazol-2-yl) ethanone with H2O2 as oxidant. Influence of temperature and catalyst amount on the oxidation reaction was evaluated. The reaction optimal conditions are as follows: molar ratio of catalyst to substrate to H2O2 is 1 : 1000 : 3000, the proper reaction temperature is 50 degrees C and reaction time lasts 5 h, and the isolated yield of 1-(1H-benzo[d] imidazol-2-yl) ethanol to 1-(1H-benzo[d] imidazol-2-yl) ethanone under the optimal reaction conditions is 57%.
引用
收藏
页数：7
相关论文
共 50 条
  • [21] Synthesis,Crystal Structure and Luminescent Property of Cadmium Complex Based on 2-(2-(1Hbenzo[d]imidazol-2-yl)benzyl)-1H-benzo[d]-imidazole
    苏文义
    李国璧
    潘荣楷
    唐妃琼
    钟玲
    刘生桂
    结构化学, 2014, 33 (06) : 909 - 914
  • [22] The crystal structure of 1,2-bis(1H-benzo[d]imidazol-2-yl)ethane-1,2-diol - N-(2-aminophenyl)-3-(1H-benzo[d]imidazol-2-yl)-2,3-dihydroxypropanamide (1/1), C32H30N8O5
    Clark, Candyce R.
    Hosten, Eric C.
    Betz, Richard
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2021, 236 (02): : 325 - 327
  • [23] Synthesis,Crystal Structure and Luminescent Property of Cadmium Complex Based on 2-(2-(1Hbenzo[d]imidazol-2-yl)benzyl)-1H-benzo[d]-imidazole
    苏文义
    李国璧
    潘荣楷
    唐妃琼
    钟玲
    刘生桂
    Chinese Journal of Structural Chemistry, 2014, (06) : 909 - 914
  • [24] Crystal structure of 2-((E)-2-(1H-benzo[d]imidazol-2-yl)vinyl)-1H-benzo[d]imidazolium dichloride dihydrate, C16H18Cl2N4O2
    Schoultz, Xandri
    Gerber, Thomas I. A.
    Hosten, Eric C.
    Betz, Richard
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2015, 230 (04): : 315 - 317
  • [25] THE USES OF ETHYL 2-(1H-BENZO[D]IMIDAZOL-2-YL)ACETATE TO SYNTHESIS PYRAZOLE, THIOPHENE, PYRIDINE AND COUMARIN DERIVATIVES WITH ANTITUMOR ACTIVITIES
    Mohareb, Rafat M.
    Gamaan, Marwa S.
    BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2018, 32 (03) : 541 - 557
  • [26] Synthesis, characterization and antimicrobial activity of some 3-(2-(1H-benzo[d]imidazol-2-yl)phenyl)-2-arylthiazolidin-4-ones
    Desai, N. C.
    Bhatt, Nayan
    Kumar, Mukesh
    Makwana, Atul
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2011, 50 (07): : 941 - 945
  • [27] Facile Synthesis of Diethyl {Aryl-[(1H-benzo[d]imidazol-2-yl)amino]methyl}phosphonates and Their Antimicrobial Activity
    Renuka, D.
    Mohan, G.
    Santhisudha, S.
    Reddy, C. Suresh
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2023, 93 (01) : 136 - 147
  • [28] Facile Synthesis of Diethyl {Aryl-[(1H-benzo[d]imidazol-2-yl)amino]methyl}phosphonates and Their Antimicrobial Activity
    D. Renuka
    G. Mohan
    S. Santhisudha
    C. Suresh Reddy
    Russian Journal of General Chemistry, 2023, 93 : 136 - 147
  • [29] N-(1H-Benzo[d]imidazol-2-yl)-1-(3-substituted phenyl) methanimines as optoelectronic and nonlinear optical materials: spectroscopic and computational approaches
    Ojo, Nathanael Damilare
    Adekusibe, Olaide Deborah
    Odozi, Nnenna Winifred
    Obi-Egbedi, Nelson Okpako
    CHEMICAL PAPERS, 2024, 78 (14) : 7775 - 7789
  • [30] Studies of 5-aryl-4-(1H-benzo[d]imidazol-2-yl)-1-(4-(naphthalen2-yl) thiazol-2-yl)pyrrolidin-2-one Derivatives
    Patel, Kandarp H.
    Patel, Yogesh S.
    ORBITAL-THE ELECTRONIC JOURNAL OF CHEMISTRY, 2015, 7 (03): : 231 - 239
12345