Synthesis, characterization and crystal structure of a manganese(III) Schiff base complex and investigation of its catalytic activity in the oxidation of benzylic alcohols

被引：66
作者：
Kargar, Hadi [1 ]
机构：
[1] Payame Noor Univ, Dept Chem, Tehran, Iran
来源：
TRANSITION METAL CHEMISTRY | 2014年 / 39卷 / 07期
关键词：
EFFICIENT OXIDATION; SELECTIVE OXIDATION; DERIVATIVES; EPOXIDATION; MILD;
D O I：
10.1007/s11243-014-9863-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Mn(III) Schiff base complex was prepared by the reaction of 6,6'-diethoxy-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol with Mn(OAc)(2)center dot 4H(2)O. The complex was characterized by physicochemical and spectroscopic methods. Also, its molecular structure was determined by single-crystal X-ray diffraction. The complex was used as a catalyst for the efficient oxidation of benzylic alcohols with tetrabutylammonium periodate. Various reaction parameters were optimized for the reaction of benzyl alcohol.
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收藏
页码：811 / 817
页数：7
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