Synthesis, characterization and crystal structure of a manganese(III) Schiff base complex and investigation of its catalytic activity in the oxidation of benzylic alcohols

被引：64
作者：
Kargar, Hadi [1 ]
机构：
[1] Payame Noor Univ, Dept Chem, Tehran, Iran
来源：
TRANSITION METAL CHEMISTRY | 2014年 / 39卷 / 07期
关键词：
EFFICIENT OXIDATION; SELECTIVE OXIDATION; DERIVATIVES; EPOXIDATION; MILD;
D O I：
10.1007/s11243-014-9863-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Mn(III) Schiff base complex was prepared by the reaction of 6,6'-diethoxy-2,2'-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol with Mn(OAc)(2)center dot 4H(2)O. The complex was characterized by physicochemical and spectroscopic methods. Also, its molecular structure was determined by single-crystal X-ray diffraction. The complex was used as a catalyst for the efficient oxidation of benzylic alcohols with tetrabutylammonium periodate. Various reaction parameters were optimized for the reaction of benzyl alcohol.
引用
收藏
页码：811 / 817
页数：7
相关论文
共 31 条
[1]   Thermogravimetric and spectroscopic characterization of trivalent lanthanide chelates with some Schiff bases [J].
Al-Shihri, ASM ;
Abdel-Fattah, HM .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 71 (02) :643-649
[2]   Selective oxidation of alcohols to carbonyl compounds and carboxylic acids with platinum group metal catalysts [J].
Anderson, R ;
Griffin, K ;
Johnston, P ;
Alsters, PL .
ADVANCED SYNTHESIS & CATALYSIS, 2003, 345 (04) :517-523
[3]   Self-assembly of dimeric MnIII-Schiff-Base complexes tuned by perchlorate anions [J].
Bermejo, Manuel R. ;
Fernandez, M. Isabel ;
Gomez-Forneas, Esther ;
Gonzalez-Noya, Ana ;
Maneiro, Marcelino ;
Pedrido, Rosa ;
Rodriguez, M. Jesu .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 24 (24) :3789-3797
[4]   AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].
BLESSING, RH .
ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38
[5]   Enantiomeric recognition of amino acid derivatives by chiral Schiff bases of calix[4]arene [J].
Durmaz, Mustafa ;
Alpaydin, Sabri ;
Sirit, Abdulkadir ;
Yilmaz, Mustafa .
TETRAHEDRON-ASYMMETRY, 2007, 18 (07) :900-905
[6]   Advances and future trends in selective oxidation and ammoxidation catalysis [J].
Grasselli, RK .
CATALYSIS TODAY, 1999, 49 (1-3) :141-153
[7]   Ruthenium(II) carbonyl complexes with tridentate Schiff bases and their antibacterial activity [J].
Jayabalakrishnan, C ;
Natarajan, K .
TRANSITION METAL CHEMISTRY, 2002, 27 (01) :75-79
[8]   Rapid and efficient biomimetic oxidation of 2-imidazolines to their corresponding imidazoles with NaIO4 catalyzed by Mn(salophen)Cl [J].
Kargar, Hadi .
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (06) :863-866
[9]  
Ley S.V., 1991, COMPREHENSIVE ORGANI, V7, P251, DOI DOI 10.1016/B978-0-08-052349-1.09002-8
[10]   Selective and efficient C-H oxidation of alkanes with hydrogen peroxide catalyzed by a manganese(III) Schiff base complex [J].
Mardani, Hamid R. ;
Golchoubian, Hamid .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 259 (1-2) :197-200
1234