Clarifying the multiple roles of confinement in zeolites: From stabilization of transition states to modification of internal diffusion rates

被引：16
作者：
Crossley, Steven P. [1 ]
Resasco, Daniel E. [1 ]
Haller, Gary L. [2 ]
机构：
[1] Univ Oklahoma, Sch Chem Biol & Mat Engn, Norman, OK 73019 USA
[2] Yale Univ, Sch Engn & Appl Sci, Dept Chem & Environm Engn, New Haven, CT 06520 USA
来源：
JOURNAL OF CATALYSIS | 2019年 / 372卷
关键词：
Zeolites; Confinement; Hydrocracking; Diffusion; Isomerization; ss-scission; ACID STRENGTH; CATALYTIC DIVERSITY; SITE PROXIMITY; ADSORPTION; ZSM-5; HYDROCRACKING; ISOMERIZATION; SELECTIVITY; SOLVATION; MOLECULES;
D O I：
10.1016/j.jcat.2019.03.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
引用
收藏
页码：382 / 387
页数：6
相关论文
共 41 条
  • [1] [Anonymous], 1975, AICHE J, DOI DOI 10.1002/AIC.690210537
  • [2] Acidity differences between inorganic solids induced by their framework structure.: A combined quantum mechanics molecular mechanics ab initio study on zeolites
    Brändle, M
    Sauer, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (07) : 1556 - 1570
  • [3] Butt J.B., 2000, REACTION KINETICS RE, P477
  • [4] INTERNAL MASS AND HEAT TRANSPORT EFFECTS ON CATALYTIC BEHAVIOR - ACTIVITY SELECTIVITY AND YIELD IN A COMPLEX REACTION SYSTEM
    BUTT, JB
    [J]. CHEMICAL ENGINEERING SCIENCE, 1966, 21 (03) : 275 - &
  • [5] Trace water amounts can increase benzene H/D exchange rates in an acidic zeolite
    Chen, Kuizhi
    Gumidyala, Abhishek
    Abdolrhamani, Maryam
    Villines, Cameron
    Crossley, Steven
    White, Jeffery L.
    [J]. JOURNAL OF CATALYSIS, 2017, 351 : 130 - 135
  • [6] SHAPE-SELECTIVE CATALYSIS IN ZEOLITES
    CSICSERY, SM
    [J]. ZEOLITES, 1984, 4 (03): : 202 - 213
  • [7] SURFACE CURVATURE EFFECTS IN PHYSISORPTION AND CATALYSIS BY MICROPOROUS SOLIDS AND MOLECULAR-SIEVES
    DEROUANE, EG
    ANDRE, JM
    LUCAS, AA
    [J]. JOURNAL OF CATALYSIS, 1988, 110 (01) : 58 - 73
  • [8] Confinement effects in the adsorption of simple bases by zeolites
    Derouane, EG
    Chang, CD
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2000, 35-6 : 425 - 433
  • [9] Introducing Catalytic Diversity into Single-Site Chabazite Zeolites of Fixed Composition via Synthetic Control of Active Site Proximity
    Di Iorio, John R.
    Nimlos, Claire T.
    Gounder, Rajamani
    [J]. ACS CATALYSIS, 2017, 7 (10): : 6663 - 6674
  • [10] Epitaxial Growth of ZSM-5@Silicalite-1: A Core-Shell Zeolite Designed with Passivated Surface Acidity
    Ghorbanpour, Arian
    Gumidyala, Abhishek
    Grabow, Lars C.
    Crossley, Steven P.
    Rimer, Jeffrey D.
    [J]. ACS NANO, 2015, 9 (04) : 4006 - 4016
12345