Comparison of the Physicochemical Properties of Carboxylic and Phosphonic Acid Self-Assembled Monolayers Created on a Ti-6Al-4V Substrate

被引：5
|
作者：
Cichomski, Michal [1 ]
Prowizor, Milena [1 ]
Kowalczyk, Dorota Anna [2 ]
Sikora, Andrzej [3 ]
Batory, Damian [4 ]
Dudek, Mariusz [5 ]
机构：
[1] Univ Lodz, Fac Chem, Dept Mat Technol & Chem, Pomorska 163, PL-90236 Lodz, Poland
[2] Univ Lodz, Fac Phys & Appl Informat, Dept Solid State Phys, Pomorska 149-153, PL-90236 Lodz, Poland
[3] Wroclaw Univ Sci & Technol, Dept Nanometrol, Fac Microsyst Elect & Photon, Janiszewskiego 11-17, PL-50372 Wroclaw, Poland
[4] Lodz Univ Technol, Dept Vehicles & Fundamentals Machine Design, Stefanowskiego 1-15, PL-90924 Lodz, Poland
[5] Lodz Univ Technol, Inst Mat Sci & Engn, Stefanowskiego 1-15, PL-90924 Lodz, Poland
来源：
MATERIALS | 2020年 / 13卷 / 22期
关键词：
carboxylic; phosphonic acid; Ti-6Al-4V alloy; adhesion; friction; nano-; microtribology; ATOMIC-FORCE MICROSCOPY; NANOTRIBOLOGICAL CHARACTERIZATION; TITANIUM SURFACES; FRETTING-FATIGUE; OXIDE; ALUMINUM; WEAR; OCTADECYLSILOXANE; STABILITY; CHEMISTRY;
D O I：
10.3390/ma13225137
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This study compared the tribological properties in nano- and millinewton load ranges of Ti-6Al-4V surfaces that were modified using self-assembled monolayers (SAMs) of carboxylic and phosphonic acids. The effectiveness of the creation of SAMs with the use of the liquid phase deposition (LPD) technique was monitored by the contact angle measurement, the surface free energy (SFE) calculation, X-ray photoelectron spectroscopy (XPS), and Fourier-transform infrared spectroscopy (FTIR) measurements. The obtained results indicated that more stable and well-ordered layers, which were characterized by the lowest values of the coefficient of friction, adhesion, and wear rate, were obtained using phosphonic acid as a surface modifier. Based on the obtained results, it was found that the Ti-6Al-4V alloy modified by phosphonic acid would be the most advantageous for practical applications, especially in micro- and nanoelectromechanical systems (MEMS/NEMS).
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页码：1 / 17
页数：17
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