Nucleation of CO2-hydrate in a porous medium

被引:62
作者
Zatsepina, OY [1 ]
Buffett, BA [1 ]
机构
[1] Univ British Columbia, Dept Earth & Ocean Sci, Vancouver, BC V6T 1Z4, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
gas hydrate; model; nucleation time; interfacial tension; electrical conductivity; porous media;
D O I
10.1016/S0378-3812(02)00032-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experiments designed to crystallize gas hydrate from dissolved CO2 in natural porous media are used to study nucleation under varying thermodynamic conditions. We recover quantitative information from these experiments using a stochastic model for the nucleation process. Estimates of the model parameters are used to determine the average time for nucleation as a function of temperature and composition. (C) 2002 Elsevier Science B.V All rights reserved.
引用
收藏
页码:263 / 275
页数:13
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