Fructose conversion in the presence of Sn(IV) catalysts exhibiting high selectivity to lactic acid

被引：28

作者：

dos Santos, Jailma Barros ^{[1
]}

Araujo de Albuquerque, Nilson Jose ^{[1
]}

de Paiva e Silva Zanta, Carmen Lucia ^{[1
]}

Meneghetti, Mario Roberto ^{[1
]}

Plentz Meneghetti, Simoni Margareti ^{[1
]}

机构：

[1] Inst Chem & Biotechnol, Maceio, Alagoas, Brazil

来源：

RSC Advances | 2015年 / 5卷 / 110期

关键词：

HYDROTHERMAL CONVERSION; SUBCRITICAL WATER; CELLULOSE; GLUCOSE; ISOMERIZATION; SUGARS; SALTS;

D O I：

10.1039/c5ra20881e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic performance of a series of Sn(IV)-based organometallic complexes in fructose conversion was studied under several reaction conditions, and the conversion, yields, and selectivity measurements of this transformation have been evaluated. The results were compared to those obtained from non-catalysed reactions and those in the presence of a conventional catalyst (H2SO4). These organometallic Sn(IV)-based catalysts demonstrated the ability to fully convert fructose into valuable chemicals. Under particular reaction conditions, lactic acid is obtained in good yields and selectivity.

引用

页码：90952 / 90959

页数：8

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