Layered structures and nanosheets of pyrimidinethiolate coordination polymers

被引：56

作者：

Beldon, P. J. ^{[1
]}

Tominaka, S. ^{[1
,2
]}

Singh, P. ^{[3
]}

Dasgupta, T. Saha ^{[3
]}

Bithell, E. G. ^{[1
]}

Cheetham, A. K. ^{[1
]}

机构：

[1] Univ Cambridge, Cambridge CB3 0FS, England

[2] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton WPI MANA, Tsukuba, Ibaraki 3050044, Japan

[3] SN Bose Natl Ctr Basic Sci, Kolkata 700098, India

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 30期

基金：

英国工程与自然科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORK; EFFECTIVE IONIC-RADII; COMPLEXES; GRAPHENE; CONDUCTIVITY; DISPERSIONS; EXFOLIATION; FABRICATION; CHEMISTRY; SOLIDS;

D O I：

10.1039/c4cc00771a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the synthesis, crystal structure and exfoliation of a new member of an important family of layered compounds: lamellar pyrimidinethiolate coordination polymers. Conductivity measurements and DFT calculations of iron(II) pyrimidine-2-thiolate show that this material and a related compound are insulators.

引用

收藏

页码：3955 / 3957

页数：3

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