Layered structures and nanosheets of pyrimidinethiolate coordination polymers

被引：56
作者：
Beldon, P. J. [1 ]
Tominaka, S. [1 ,2 ]
Singh, P. [3 ]
Dasgupta, T. Saha [3 ]
Bithell, E. G. [1 ]
Cheetham, A. K. [1 ]
机构：
[1] Univ Cambridge, Cambridge CB3 0FS, England
[2] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton WPI MANA, Tsukuba, Ibaraki 3050044, Japan
[3] SN Bose Natl Ctr Basic Sci, Kolkata 700098, India
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 30期
基金：
英国工程与自然科学研究理事会;
关键词：
METAL-ORGANIC FRAMEWORK; EFFECTIVE IONIC-RADII; COMPLEXES; GRAPHENE; CONDUCTIVITY; DISPERSIONS; EXFOLIATION; FABRICATION; CHEMISTRY; SOLIDS;
D O I：
10.1039/c4cc00771a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the synthesis, crystal structure and exfoliation of a new member of an important family of layered compounds: lamellar pyrimidinethiolate coordination polymers. Conductivity measurements and DFT calculations of iron(II) pyrimidine-2-thiolate show that this material and a related compound are insulators.
引用
收藏
页码：3955 / 3957
页数：3
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