Alternating assembly structure of the same dye and modification material in quasi-solid state dye-sensitized solar cell

被引:12
作者
Ma, Beibei [1 ]
Gao, Rui [1 ]
Wang, Liduo [1 ]
Luo, Fen [1 ]
Zhan, Chun [1 ]
Li, Jiaoli [1 ]
Qiu, Yong [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
Dye-sensitized solar cell; Alternating assembly structure; Dye-modification material; N3-dye; Molecular aggregation; LONG-TERM STABILITY; NANOCRYSTALLINE TIO2; ELECTRON-TRANSFER; PERFORMANCE; CONVERSION; POWER;
D O I
10.1016/j.jphotochem.2008.11.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Only one sort of dye and a dye-modification material is used to form an alternating assembly structure in dye-sensitized solar cell. The alternating assembly can increase the adsorption of dye sensitizer, prohibit the aggregation of the dye, and retard the recombination reaction. These effects are investigated by ultraviolet-visible spectrum, Fourier transform infrared spectrum, transient photovoltages, current density-voltage characteristics and dark current measurements. The photon-electron conversion efficiency of the cell with alternating assembly structure rise by 16%, from 3.86% to 4.49% under AM 1.5 irradiation. And the stability of the cell is also improved. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:33 / 38
页数:6
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