The Past, Present, and Future of Molecular Gels. What Is the Status of the Field, and Where Is It Going?

被引:576
|
作者
Weiss, Richard G. [1 ,2 ]
机构
[1] Georgetown Univ, Dept Chem, Washington, DC 20057 USA
[2] Georgetown Univ, Inst Soft Matter Synth & Metrol, Washington, DC 20057 USA
基金
美国国家科学基金会;
关键词
X-RAY; SUPRAMOLECULAR GELS; ORGANOGEL FORMATION; WEIGHT GELATORS; ORGANIC FLUIDS; STRUCTURAL DEVELOPMENT; RHEOLOGICAL PROPERTIES; PROTEIN-STRUCTURE; MATERIALS SCIENCE; INSTANT GELATION;
D O I
10.1021/ja503363v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Perspective is presented on the history and current understanding of molecular gels and the factors that must be considered to characterize them. The abilities of the most important structural, dynamic, and rheological tools available currently to provide the information necessary to follow the formation of a molecular gel from its initial sol phase and then to define it at different distance and time scales are discussed. Approaches to determining a priori when a molecule will gelate a selected liquid, as well as possible methodologies for overcoming current limitations in understanding molecular gels, are presented. Finally, some of the many potential and realized applications for these materials are enumerated.
引用
收藏
页码:7519 / 7530
页数:12
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