Versatile chain transfer agents for reversible addition fragmentation chain transfer (RAFT) polymerization to synthesize functional polymeric architectures

被引：179
作者：
Perrier, S [1 ]
Takolpuckdee, P [1 ]
Westwood, J [1 ]
Lewis, DM [1 ]
机构：
[1] Univ Leeds, Dept Colour & Polymer Chem, Leeds LS2 9JT, W Yorkshire, England
来源：
MACROMOLECULES | 2004年 / 37卷 / 08期
关键词：
D O I：
10.1021/ma035468b
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report the syntheses and uses of versatile chain transfer agents (CTAs) that produce well-controlled macromolecular architectures with specific chain-end functionalities, via reversible addition fragmentation chain transfer (RAFT) polymerization). Examples of architectures are given, including amphiphilic copolymers and block copolymers incorporating a biodegradable block. These CTAs are also used for the grafting of poly(styrene), poly(methyl methacrylate) and poly(methyl acrylate) from cotton.
引用
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页码：2709 / 2717
页数：9
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