Visual Voltammogram at an Array of Closed Bipolar Electrodes in a Ladder Configuration

被引:15
作者
Borchers, Janis S. [1 ]
Riusech, Olga [1 ]
Rasmussen, Eric [1 ]
Anand, Robbyn K. [1 ]
机构
[1] Iowa State Univ, Dept Chem, 1605 Gilman Hall,2415 Osborn Dr, Ames, IA 50011 USA
关键词
Bipolar electrochemistry; Voltammetry; Electrogenerated chemiluminescence; Visual voltammogram; Flow cell; CELL; POLY(DIMETHYLSILOXANE); CONSTRUCTION; MICROCHANNEL; VOLTAMMETRY; SEPARATION; GRADIENT; PLATFORM; SENSOR;
D O I
10.1007/s41664-019-00098-9
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this paper, we report a method for obtaining a visual voltammogram at a linear array of closed wireless bipolar electrodes (BPEs). This advancement is significant, because the visual voltammogram captures the entire current-potential (i-E) relationship of a faradaic reaction in one image and is continuously generated over time. Therefore, we anticipate that this method will allow monitoring in redox systems that change over time. Further, the use of a linear array of BPEs eliminates the need to use a potentiostat and can be carried out with a simple DC power supply. Our experimental and numerical results demonstrate that the visual voltammogram is similar to a linear sweep voltammogram and therefore, information about the faradaic process can be extracted from the wave position, height, and shape.
引用
收藏
页码:150 / 159
页数:10
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