Crystal structure of polynuclear pivalate Ni(II) complexes with butanediol

被引：3
|
作者：
Romanenko, G. V. [1 ]
Kuznetsova, O. V. [1 ]
Fursova, E. Yu. [1 ]
Ovcharenko, V. I. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Inst Int Tomog Ctr, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 03期
关键词：
nickel(II); polynuclear compounds; pivalates; butanediol; single crystal X-ray diffraction study; SINGLE-MOLECULE MAGNET; HETEROSPIN COMPLEXES;
D O I：
10.1134/S0022476614030135
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Using single crystal X-ray diffraction the structure of polynuclear [Ni-6(OH)(4)(Piv)(7)(HOC4H8O)(HPiv)(4)], {K-4[Ni-12(CO3)(2)(Piv)(16)(OH)(8)(HOC4H8OH)(2)]}HPiv, {[Ni-6(OH)(4)(Piv)(6)(HOC4H8O)(Me2CO)(HOC4H8OH)(2)](4)x(Piv)(4)}, and {K[Ni2L2(Piv)(3)]}(a) complexes, where HOC4H8OH is 1,4-butanediol, HPiv is pivalic acid, and L is the anion of nitroxyl radical 2,2,5,5-tetramethyl-4-(3',3',3'-trifluoro-2'-oxy-1'-propenyl)-3-imidazolin-1-oxyl is determined.
引用
收藏
页码：481 / 487
页数：7
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