Application of dimeric orthopalladate complex of homoveratrylamine as an efficient catalyst in the Heck cross-coupling reaction

被引：41

作者：

Hajipour, Abdol R. ^{[1
,2
]}

Karami, Kazem ^{[2
]}

Pirisedigh, Azadeh ^{[1
]}

Ruoho, Arnold E. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Pharmacol, Sch Med, Madison, WI 53706 USA

[2] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 16期

关键词：

Orthopalladate; Homoveratrylamine; Catalyst; Heck reaction; N-HETEROCYCLIC CARBENE; PHOSPHA-PALLADACYCLES; PALLADIUM COMPLEXES; CYCLOMETALATED COMPLEXES; MOLECULAR-STRUCTURE; ARYL CHLORIDES; PRIMARY AMINES; TRICYCLOHEXYLPHOSPHINE ADDUCTS; STRUCTURAL-CHARACTERIZATION; CYCLOPALLADATED COMPLEXES;

D O I：

10.1016/j.jorganchem.2009.04.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [Pd{C6H2(CH2CH2NH2)-(OMe)(2),3,4} (mu-Br)](2) complex of homoveratrylamine was synthesized and its application in the Heck coupling reaction was studied. This complex had been demonstrated to be active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides. The cross-coupled products were produced in excellent yields in a short reaction time using catalytic amounts of [Pd{C6H2(CH2CH2NH2)-(OMe)(2),3,4} (mu-Br)](2) complex in N-methyl-2-pyrrolidinone (NMP at 130 degrees C). (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：2548 / 2554

页数：7

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