Densification, Structure, and Thermophysical Properties of Ytterbium-Gadolinium Zirconate Ceramics

被引:45
作者
Liu, Zhan-Guo [1 ]
Ouyang, Jia-Hu [1 ]
Zhou, Yu [1 ]
Li, Jing [1 ]
Xia, Xiao-Liang [1 ]
机构
[1] Harbin Inst Technol, Dept Mat Sci, Inst Adv Ceram, Harbin 150001, Peoples R China
关键词
THERMAL-BARRIER COATINGS; CONDUCTIVITY; EXPANSION; LANTHANUM;
D O I
10.1111/j.1744-7402.2008.02289.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
(YbxGd1-x)(2)Zr2O7 (0 <= x <= 1.0) ceramic powders synthesized with the chemical-coprecipitation and calcination method were pressureless-sintered at 1550-1700 degrees C to develop new thermal barrier oxides with a lower thermal conductivity than yttria-stabilized zirconia ceramics. (YbxGd1-x)(2)Zr2O7 ceramics exhibit a defective fluorite-type structure. The linear thermal expansion coefficients of (YbxGd1-x)(2)Zr2O7 ceramics increase with increasing temperature from room temperature to 1400 degrees C. The measured thermal conductivity of (YbxGd1-x)(2)Zr2O7 ceramics first gradually decrease with increasing temperature and then slightly increase above 800 degrees C because of the increased radiation contribution. YbGdZr2O7 ceramics have the lowest thermal conductivity among all the composition combinations studied.
引用
收藏
页码:485 / 491
页数:7
相关论文
共 23 条
[1]  
Berman R., 1976, THERMAL CONDUCTION S, P45
[2]   Ceramic materials for thermal barrier coatings [J].
Cao, XQ ;
Vassen, R ;
Stoever, D .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2004, 24 (01) :1-10
[3]   Mechanics-based scaling laws for the durability of thermal barrier coatings [J].
Evans, AG ;
He, MY ;
Hutchinson, JW .
PROGRESS IN MATERIALS SCIENCE, 2001, 46 (3-4) :249-271
[4]   Microstructure and phase transformation of zirconia-based ternary oxides for thermal barrier coating applications [J].
Huang, Xiao ;
Zakurdaev, Andrey ;
Wang, Dongmei .
JOURNAL OF MATERIALS SCIENCE, 2008, 43 (08) :2631-2641
[5]   Thermal barrier coatings design with increased reflectivity and lower thermal conductivity for high-temperature turbine applications [J].
Kelly, MJ ;
Wolfe, DE ;
Singh, J ;
Eldridge, J ;
Zhu, DM ;
Miller, R .
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2006, 3 (02) :81-93
[6]   The linear thermal expansion and the thermal diffusivity measurements for near-stoichiometric (U, Ce)O2 solid solutions [J].
Kim, DJ ;
Kim, YS ;
Kim, SH ;
Kim, JH ;
Yang, JH ;
Lee, YW ;
Kim, HS .
THERMOCHIMICA ACTA, 2006, 441 (02) :127-131
[7]  
Kubaschewski O., 1993, Materials Thermochemistry, P257
[8]   Thermal conductivity and thermal expansion coefficients of the lanthanum rare-earth-element zirconate system [J].
Lehmann, H ;
Pitzer, D ;
Pracht, G ;
Vassen, R ;
Stöver, D .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2003, 86 (08) :1338-1344
[9]   Emerging materials and processes for thermal barrier systems [J].
Levi, CG .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2004, 8 (01) :77-91
[10]  
MANSAL NP, 2007, MAT SCI ENG A-STRUCT, V459, P192