A Manganese(II) Coordination Polymer with the Ligands Azide and Picolinate: Synthesis, Structure, and Magnetic Properties

被引：2
作者：
Yang, Qian [1 ]
Liu, Sui-Jun [1 ]
Zhang, Ying-Hui [1 ]
机构：
[1] Nankai Univ, MOE Innovat Team China IRT13022, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 8-9期
基金：
中国国家自然科学基金;
关键词：
Azide; Manganese; Picolinic acid; Magnetic properties; METAL-ORGANIC FRAMEWORKS; BRIDGED COBALT(II); COMPLEXES; NICKEL(II); SYSTEMS; DESIGN; COLIGANDS; BEHAVIOR; SOLIDS; ACID;
D O I：
10.1002/zaac.201400016
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The two dimensional Mn-II coordination polymer [Mn-3(pic)(2)(N-3)(4)(CH3OH)](n) (1) with the ligands azide and picolinic acid (Hpic) was synthesized and characterized by IR spectroscopy, elemental analysis, and powder and single-crystal X-ray diffraction analysis. Meanwhile, analysis of the magnetic properties revealed antiferromagnetic exchange for polymer 1.
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页码：1555 / 1558
页数：4
相关论文
共 46 条
[1]   Synthesis, structural characterization, magnetic behavior, and single crystal EPR spectra of three new one-dimensional manganese azido systems with FM, alternating FM-AF, and AF coupling [J].
Abu-Youssef, MAM ;
Escuer, A ;
Gatteschi, D ;
Goher, MAS ;
Mautner, FA ;
Vicente, R .
INORGANIC CHEMISTRY, 1999, 38 (25) :5716-5723
[2]   A-Site-Ordered Perovskite MnCu3V4O12 with a 12-Coordinated Manganese(II) [J].
Akizuki, Yasuhide ;
Yamada, Ikuya ;
Fujita, Koji ;
Nishiyama, Norimasa ;
Irifune, Tetuo ;
Yajima, Takeshi ;
Kageyama, Hiroshi ;
Tanaka, Katsuhisa .
INORGANIC CHEMISTRY, 2013, 52 (19) :11538-11543
[3]   Metal-organic frameworks as solid magnesium electrolytes [J].
Aubrey, M. L. ;
Ameloot, R. ;
Wiers, B. M. ;
Long, J. R. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (02) :667-671
[4]  
Biani FD., 2000, Inorg Chem, V39, P3221, DOI DOI 10.1021/IC000005X
[5]  
Bruker AXS, 1998, SAINT Software Reference Manual
[6]   Four Low-Dimensional Cobalt(II) Coordination Polymers Based on a New Isophthalic Acid Derivative: Syntheses, Crystal Structures, and Properties [J].
Chang, Xin-Hong ;
Ma, Lu-Fang ;
Hui, Guo ;
Wang, Li-Ya .
CRYSTAL GROWTH & DESIGN, 2012, 12 (07) :3638-3646
[7]   A Controllable Gate Effect in Cobalt(II) Organic Frameworks by Reversible Structure Transformations [J].
Chen, Qiang ;
Chang, Ze ;
Song, Wei-Chao ;
Song, Han ;
Song, Hai-Bin ;
Hu, Tong-Liang ;
Bu, Xian-He .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (44) :11550-11553
[8]   A Cu(I) metal-organic framework with 4-fold helical channels for sensing anions [J].
Chen, Yong-Qiang ;
Li, Guo-Rong ;
Chang, Ze ;
Qu, Yang-Kun ;
Zhang, Ying-Hui ;
Bu, Xian-He .
CHEMICAL SCIENCE, 2013, 4 (09) :3678-3682
[9]   Metal-Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal-Organic Materials [J].
Cook, Timothy R. ;
Zheng, Yao-Rong ;
Stang, Peter J. .
CHEMICAL REVIEWS, 2013, 113 (01) :734-777
[10]   Functional Mixed Metal-Organic Frameworks with Metalloligands [J].
Das, Madhab C. ;
Xiang, Shengchang ;
Zhang, Zhangjing ;
Chen, Banglin .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (45) :10510-10520
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