A mesoporous ruthenium silica hybrid aerogel with outstanding catalytic properties in the synthesis of N,N-diethylformamide from CO2, H2 and diethylamine

被引：58

作者：

Schmid, L ^{[1
]}

Rohr, M ^{[1
]}

Baiker, A ^{[1
]}

机构：

[1] ETH Zentrum, Swiss Fed Inst Technol, Tech Chem Lab, CH-8092 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 22期

关键词：

D O I：

10.1039/a906956i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mesoporous ruthenium silica hybrid aerogel containing well dispersed bidentate RuCl2[Ph2P(CH2)(3)PPh2](2) complexes, synthesized using a sol-gel method, affords turnover frequencies up to 18400 h(-1) and 100% selectivity from CO2, H-2 and diethylamine for the formation of N,N-diethylformamide.

引用

页码：2303 / 2304

页数：2

共 10 条

[1] CARBON-DIOXIDE AS AN ALTERNATIVE C1 SYNTHETIC UNIT - ACTIVATION BY TRANSITION-METAL COMPLEXES [J].

BEHR, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (05) :661-678

[2]

Broekhoff J.C.P., 1979, Studies in surface science and catalysis, P663, DOI [DOI 10.1016/S0167-2991(09)60243-3, 10.1016/S0167-2991(09)60243-3]

[3] HOMOGENEOUS HYDROGENATION OF CARBON-DIOXIDE [J].

JESSOP, PG ;

IKARIYA, T ;

NOYORI, R .

CHEMICAL REVIEWS, 1995, 95 (02) :259-272

[4] Homogeneous catalysis in supercritical fluids: Hydrogenation of supercritical carbon dioxide to formic acid, alkyl formates, and formamides [J].

Jessop, PG ;

Hsiao, Y ;

Ikariya, T ;

Noyori, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (02) :344-355

[5]

Krocher O, 1997, CHIMIA, V51, P48

[6] Silica hybrid gel catalysts containing Group(VIII) transition metal complexes: Preparation, structural, and catalytic properties in the synthesis of N,N-dimethylformamide and methyl formate from supercritical carbon dioxide [J].

Krocher, O ;

Koppel, RA ;

Froba, M ;

Baiker, A .

JOURNAL OF CATALYSIS, 1998, 178 (01) :284-298

[7] Silica hybrid gel catalysts containing ruthenium complexes:: influence of reaction parameters on the catalytic behaviour in the synthesis of N,N-dimethylformamide from carbon dioxide [J].

Kröcher, O ;

Köppel, RA ;

Baiker, A .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 140 (02) :185-193

[8] CARBON-DIOXIDE AS A RAW-MATERIAL - THE SYNTHESIS OF FORMIC-ACID AND ITS DERIVATIVES FROM CO2 [J].

LEITNER, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (20) :2207-2221

[9] POLYPHOSPHINE COMPLEXES OF RUTHENIUM(II) [J].

MASON, R ;

MEEK, DW ;

SCOLLARY, GR .

INORGANICA CHIMICA ACTA, 1976, 16 (JAN) :L11-L12

[10]

SCHMID L, 1999, IN PRESS MICROPOR ME

← 1 →