A new method for the generation of nitriles from aldoximes

被引：32

作者：

Jose, B ^{[1
]}

Sulatha, MS ^{[1
]}

Pillai, PM ^{[1
]}

Prathapan, S ^{[1
]}

机构：

[1] Cochin Univ Sci & Technol, Dept Appl Chem, Cochin 682022, Kerala, India

来源：

SYNTHETIC COMMUNICATIONS | 2000年 / 30卷 / 08期

关键词：

D O I：

10.1080/00397910008087179

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild and efficient method for the stereoselective dehydration of alpha-aldoximes to the corresponding nitriles is described which utilises methyl (carboxysulfamoyl)triethylammonium hydroxide inner salt (Burgess reagent) as the dehydrating agent.

引用

页码：1509 / 1514

页数：6

共 25 条

[1] AIZPURUA JM, 1983, NOUV J CHIM, V7, P465
[2] REACTIONS OF AN N-SULFONYLAMINE INNER SALT
ATKINS, GM
BURGESS, EM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (17) : 4744 - &
[3] ATTANASI O, 1983, SYNTHESIS-STUTTGART, P741
[4] Burgess E.M., 1977, Org. Syn, V56, P40, DOI DOI 10.15227/ORGSYN.056.0040
[5] THERMAL REACTIONS OF ALKYL N-CARBOMETHOXYSULFAMATE ESTERS
BURGESS, EM
PENTON, HR
TAYLOR, EA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1973, 38 (01) : 26 - 31
[6] AN EFFICIENT CHEMOSELECTIVE SYNTHESIS OF NITRILES FROM PRIMARY AMIDES
CLAREMON, DA
PHILLIPS, BT
[J]. TETRAHEDRON LETTERS, 1988, 29 (18) : 2155 - 2158
[7] TOTAL SYNTHESIS OF ELFAMYCINS - AURODOX AND EFROTOMYCIN .1. STRATEGY AND CONSTRUCTION OF KEY INTERMEDIATES
DOLLE, RE
NICOLAOU, KC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (06) : 1691 - 1694
[8] STEREOSELECTIVE THERMAL REARRANGEMENT OF SYN-7-(1,2-BUTADIENYL)-1-METHYLBICYCLO[2.2.1]HEPT-2-ENE[SYN-7-(3-METHYLALLENYL)-1-METHYLNORBORNENE]
DUNCAN, JA
HENDRICKS, RT
KWONG, KS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (23) : 8433 - 8442
[9] FATIADI AJ, CHEM FUNCTIONAL G SC, P1057
[10] STEREOSPECIFIC CIS-PYRETHROID SYNTHESIS FROM CYCLOPROPENES, USING A CARBANION SYNTHON .2. PREPARATION OF CIS-CHRYSANTHEMIC AND CIS-PYRETHRIC DERIVATIVES
FRANCKNEUMANN, M
MIESCH, M
KEMPF, H
[J]. TETRAHEDRON, 1987, 43 (05) : 853 - 858

← 1 2 3 →