Convenient direct syntheses of novel fused-ring CB4N5 systems by nitrile hydroboration

被引：5

作者：

Coult, R

Fox, MA

Rand, B

Wade, K

Westwood, AVK

机构：

[1] UNIV DURHAM, DEPT CHEM, SCI LABS, DURHAM DH1 3LE, ENGLAND

[2] UNIV LEEDS, SCH MAT, LEEDS LS2 9JT, W YORKSHIRE, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 19期

关键词：

D O I：

10.1039/a705523d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions between B2H6 or BH3 . thf (thf = tetrahydrofuran) and nitriles RC=N (R = Me, Et, Bu-t or CH2F), previously known to generate borazines (RCH2NBH)(3) have been found to generate also 25-37% yields of novel carboraza bicyclic systems related to dihydronaphthalene, H3B4N5(RCH2)(4)CHR, thus affording for the first time a direct route from commercially available acyclic reagents into mixed carbon-boron-nitrogen heterocyclic chemistry.

引用

页码：3411 / 3413

页数：3

共 20 条

[1]

BUHL M, 1992, J AM CHEM SOC, V114, P477, DOI 10.1021/ja00028a013

[2] C-13 NMR studies on carboranes and derivatives: Experimental/calculational correlations [J].