Blending based polyacrylonitrile/poly(vinyl alcohol) membrane for rechargeable lithium ion batteries

被引:64
作者
He, Chunfeng [1 ]
Liu, Jiuqing [1 ]
Li, Jie [1 ]
Zhu, Fangfang [1 ]
Zhao, Haijun [1 ]
机构
[1] Cent S Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China
基金
中国国家自然科学基金;
关键词
Polyacrylonitrile; Poly(vinyl alcohol); Gel polymer electrolyte; Lithium ion battery; INDUCED PHASE-SEPARATION; POLYMER ELECTROLYTE; SULFUR BATTERIES; ELECTROCHEMICAL PERFORMANCE; MONTMORILLONITE; INHIBITION; STABILITY;
D O I
10.1016/j.memsci.2018.05.013
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A gel polymer electrolyte based on polyacrylonitrile (PAN)/poly(vinyl alcohol) (PVA) blending membrane have been fabricated through non-solvent induced phase separation (NIPS) method followed by activation in liquid electrolyte of 1.0M LiPF6 in carbonate solvent. The blending compatibility of PVA/PAN is investigated through thermodynamics analyses and demonstrates the miscibility of PAN/PVA blending system. The blending membranes with weight ratio of PVA/PAN = 10: 90 and 20: 80 have great effect on morphology of both top and bottom surface. This characteristic exhibits the high electrolyte uptake (up to 585%), acceptable thermal stability, excellent ionic conductivity and electrochemical stability (up to 5.28 V). The application of PAN/PVA blending membrane has been demonstrated by a coin cell using Li metal as counter electrode at 1C, resulting in better long-term cycle stability in comparison to cells with Celgard2320 separator and the highest capacity retention of 96%.
引用
收藏
页码:30 / 37
页数:8
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