Mechanical and Thermal Properties of Toughened Poly(L-lactic) Acid and Lignin Blends

被引:1
作者
Mu, Chunyu [1 ]
Xue, Liyuan [1 ]
Zhu, Jun [1 ]
Jiang, Man [1 ]
Zhou, Zuowan [1 ]
机构
[1] Southwest Jiaotong Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Adv Technol Mat, Chengdu 610031, Peoples R China
基金
中国国家自然科学基金;
关键词
Poly(L-lactic) acid; Lignin; Toughening; Heterogeneous nucleation; Fully degradable blends; OIL PALM BIOMASS; PHYSICAL-PROPERTIES; CRYSTALLIZATION; DEGRADATION; COMPOSITES; PLA;
D O I
10.15376/biores.9.3.5557-5566
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
Fully degradable poly(L-lactic) acid (PLLA) and lignin blends were prepared using the melt blending method. The impact strength of PLLA was dramatically improved by 52.4% and 36.6% with the addition of 5 wt% and 10 wt% of lignin, respectively. Meanwhile, the Young's modulus was maintained. Polarized optical microscopy (POM) results indicated that lignin served as a nucleating agent for the heterogeneous crystallization of PLLA in blends, which was responsible for the improvement in the impact strength. The introduced lignin also promoted the cold-crystallization of PLLA, which was demonstrated by differential scanning calorimetry (DSC). The blends of PLLA with lignin are considered to be a promising material because of the improved toughness, the full degradability, and the lower price compared with pure PLLA.
引用
收藏
页码:5557 / 5566
页数:10
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