Synthesis and characterization of organophosphine/phosphite stabilized N-silver(I) succinimide: crystal structure of [(Ph3P)3 • AgNC4H4O2]

被引：15

作者：

Tao, Xian ^{[1
]}

Li, Yue-Qin ^{[1
]}

Xu, Hui-Hua ^{[1
]}

Wang, Ning ^{[1
]}

Du, Fang-Li ^{[1
]}

Shen, Ying-Zhong ^{[1
]}

机构：

[1] Nanjing Univ Aeronaut & Astronaut, Sch Mat Sci & Engn, Dept Appl Chem, Nanjing 210016, Peoples R China

来源：

POLYHEDRON | 2009年 / 28卷 / 06期

关键词：

N-silver(I) succinimide; Organophosphine; Phosphite; Crystal structure; CHEMICAL-VAPOR-DEPOSITION; SCALE INTEGRATION APPLICATIONS; COPPER-BASED METALLIZATION; SILVER(I) COMPLEXES; PHOSPHINE LIGAND; TRIPHENYLPHOSPHINE; CHEMISTRY; OLEFIN; TRIMETHYLVINYLSILANE; TEMPERATURE;

D O I：

10.1016/j.poly.2009.02.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six organophosphite stabilized N-silver(I) succinimide complexes of the type Ln center dot AgNC4H4O2 (L=PPh3; n=1, 2a; n =2, 2b; n =3, 2c; L=P(OEt)(3); n=1, 2d; n=2, 2e; n =3, 2f) have been prepared by reacting (AgNC4O2], which can be synthesized from succinimide and excessive Ag2O in boiling water, with triphenylphospine or triethylphosphite in dichloromethane under a nitrogen atmosphere. These complexes were obtained in high yield and characterized by elemental analysis. H-1, C-13(H) NMR, IR spectroscopy and thermal analysis (TG and DSC). The molecular structure of 2c has been determined by X-ray single crystal analysis, in which the silver atom is in distorted tetrahedral geometry. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：1191 / 1195

页数：5

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