A Promising Nano-Insulating-Oil for Industrial Application: Electrical Properties and Modification Mechanism

被引:40
作者
Chen, Jiaqi [1 ]
Sun, Potao [1 ]
Sima, Wenxia [1 ]
Shao, Qianqiu [1 ]
Ye, Lian [1 ]
Li, Chuang [1 ]
机构
[1] Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Se, Chongqing 400030, Peoples R China
基金
中国国家自然科学基金;
关键词
C-60; nanoparticles; electrical properties; insulating oil; modification mechanism; thermally stimulated current (TSC); CHARGE-TRANSPORT; BREAKDOWN; IMPULSE; C-60; DISPERSIONS; SOLUBILITY; NANOFLUIDS; STABILITY;
D O I
10.3390/nano9050788
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Despite being discovered more than 20 years ago, nanofluids still cannot be used in the power industry. The fundamental reason is that nano-insulating oil has poor stability, and its electrical performance decreases under negative impulse voltage. We found that C-60 nanoparticles can maintain long-term stability in insulating oil without surface modification. C-60 has strong electronegativity and photon absorption ability, which can comprehensively improve the electrical performance of insulating oil. This finding has great significance for the industrial application of nano-insulating oil. In this study, six concentrations of nano-C-60 modified insulating oil (CMIO) were prepared, and their breakdown strength and dielectric properties were tested. The thermally stimulated current (TSC) curves of fresh oil (FO) and CMIO were experimentally determined. The test results indicate that C-60 nanoparticles can simultaneously improve the positive and negative lightning impulse and power frequency breakdown voltage of insulating oil, while hardly increasing dielectric loss. At 150 mg/L, the positive and negative lightning impulse breakdown voltages of CMIO increased by 7.51% and 8.33%, respectively, compared with those of FO. The AC average breakdown voltage reached its peak (18.0% higher compared with FO) at a CMIO concentration of 200 mg/L. Based on the test results and the special properties of C-60, we believe that changes in the trap parameters, the strong electron capture ability of C-60, and the absorption capacity of C-60 for photons enhanced the breakdown performance of insulating oil by C-60 nanoparticles.
引用
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页数:24
相关论文
共 54 条
[1]   Effects of ageing conditions on degradation of acrylonitrile butadiene rubber filled with heat-treated ZnO star-shaped particles in rapeseed biodiesel [J].
Akhlaghi, S. ;
Pourrahimi, A. M. ;
Sjostedt, C. ;
Bellander, M. ;
Hedenqvist, M. S. ;
Gedde, U. W. .
POLYMER DEGRADATION AND STABILITY, 2017, 138 :27-39
[2]  
[Anonymous], 1995, 601561995 IEC
[3]  
[Anonymous], 2017, INTRO PERCOLATION TH, DOI DOI 10.1201/9781315274386
[4]  
ASTM, 2000, D34872000II ASTM INT
[5]   Percolation and tunneling in composite materials [J].
Balberg, I ;
Azulay, D ;
Toker, D ;
Millo, O .
INTERNATIONAL JOURNAL OF MODERN PHYSICS B, 2004, 18 (15) :2091-2121
[6]   Relating Colloidal Stability of Fullerene (C60) Nanoparticles to Nanoparticle Charge and Electrokinetic Properties [J].
Chen, Kai Loon ;
Elimelech, Menachem .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (19) :7270-7276
[7]  
Chen R., 1981, ANAL THERMALLY STIMU
[8]   Preparation and heat transfer properties of nanoparticle-in-transformer oil dispersions as advanced energy-efficient coolants [J].
Choi, C. ;
Yoo, H. S. ;
Oh, J. M. .
CURRENT APPLIED PHYSICS, 2008, 8 (06) :710-712
[9]  
Choi S.U. S., 1995, Enhancing thermal conductivity of fluids with nanoparticles, V66, pa
[10]   Experimental stability analysis of different water-based nanofluids [J].
Fedele, Laura ;
Colla, Laura ;
Bobbo, Sergio ;
Barison, Simona ;
Agresti, Filippo .
NANOSCALE RESEARCH LETTERS, 2011, 6