Zn(II)-Benzotriazolate Clusters Based Amide Functionalized Porous Coordination Polymers with High CO2 Adsorption Selectivity

被引：65
作者：
Chen, Yong-Qiang
Qu, Yang-Kun
Li, Guo-Rong
Zhuang, Zhan-Zhong
Chang, Ze [1 ]
Hu, Tong-Liang
Xu, Jian
Bu, Xian-He
机构：
[1] Nankai Univ, Dept Chem, TKL Metal & Mol Based Mat Chem, Tianjin 300071, Peoples R China
来源：
INORGANIC CHEMISTRY | 2014年 / 53卷 / 17期
基金：
美国国家科学基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; GAS-ADSORPTION; HYDROGEN-SORPTION; CAPTURE; TOPOLOGY; POLYHEDRON; SEPARATION; BINDING; STORAGE; LIGAND;
D O I：
10.1021/ic500788z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new porous coordination polymers (PCPs) based on different nanosized C-3 symmetry ligands and Zn(II)-benzotriazolate clusters have been synthesized solvothermally. Both of the desolvated complexes show selective uptake of CO2 over CH4 and N-2 at ambient temperature.
引用
收藏
页码：8842 / 8844
页数：3
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