A Highly Flexible and Lightweight MnO2/Graphene Membrane for Superior Zinc-Ion Batteries

被引:271
作者
Wang, Jinjin [1 ,2 ]
Wang, Jian-Gan [1 ,2 ]
Liu, Huanyan [1 ,2 ]
You, Zongyuan [1 ,2 ]
Li, Zhen [1 ,2 ]
Kang, Feiyu [3 ]
Wei, Bingqing [4 ]
机构
[1] Northwestern Polytech Univ, Sch Mat Sci & Engn, Ctr Nano Energy Mat, State Key Lab Solidificat Proc, Xian 710072, Peoples R China
[2] Shaanxi Joint Lab Graphene NPU, Xian 710072, Peoples R China
[3] Tsinghua Univ, Shenzhen Key Lab Graphene Based Mat, Engn Lab Functionalized Carbon Mat, Grad Sch Shenzhen, Shenzhen 518055, Peoples R China
[4] Univ Delaware, Dept Mech Engn, Newark, DE 19716 USA
基金
中国国家自然科学基金;
关键词
graphene; high energy density; MnO; (2); nanocomposite; zinc‐ ion batteries; ENERGY-STORAGE; MECHANISMS; COMPOSITE; ELECTRODE; CATHODE; DESIGN; ALPHA; V2O5;
D O I
10.1002/adfm.202007397
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Batteries powering next-generation flexible and wearable electronic devices require superior mechanical bendability and foldability. Herein, a self-standing hybrid nanoarchitecture constructed by ultralong MnO2 nanowires and graphene nanosheets as an advanced and lightweight cathodes for flexible and foldable zinc-ion batteries (ZIBs) is designed and fabricated. The new-designed batteries exhibit not only a high energy density of 436 Wh kg(-1) based on the total cathode mass but also good 2000-cycling durability. More importantly, the shape-deformable ZIBs can be operated without any capacity loss under both bent and folded circumstances. The foldable ZIBs with high energy density and long lifetime hold great promise for smart and wearable electronics.
引用
收藏
页数:9
相关论文
共 55 条
[1]   A High-Rate and Stable Quasi-Solid-State Zinc-Ion Battery with Novel 2D Layered Zinc Orthovanadate Array [J].
Chao, Dongliang ;
Zhu, Changrong ;
Song, Ming ;
Liang, Pei ;
Zhang, Xiao ;
Nguyen Huy Tiep ;
Zhao, Haofei ;
Wang, John ;
Wang, Rongming ;
Zhang, Hua ;
Fan, Hong Jin .
ADVANCED MATERIALS, 2018, 30 (32)
[2]   Zn2+ Pre-Intercalation Stabilizes the Tunnel Structure of MnO2 Nanowires and Enables Zinc-Ion Hybrid Supercapacitor of Battery-Level Energy Density [J].
Chen, Qiang ;
Jin, Jialun ;
Kou, Zongkui ;
Liao, Cong ;
Liu, Ziang ;
Zhou, Liang ;
Wang, John ;
Mai, Liqiang .
SMALL, 2020, 16 (14)
[3]   Folding Paper-Based Lithium-Ion Batteries for Higher Areal Energy Densities [J].
Cheng, Qian ;
Song, Zeming ;
Ma, Teng ;
Smith, Bethany B. ;
Tang, Rui ;
Yu, Hongyu ;
Jiang, Hanqing ;
Chan, Candace K. .
NANO LETTERS, 2013, 13 (10) :4969-4974
[4]   Phase evolution of an alpha MnO2-based electrode for pseudo-capacitors probed by in operando Raman spectroscopy [J].
Cheng, Shuang ;
Yang, Lufeng ;
Chen, Dongchang ;
Ji, Xu ;
Jiang, Zhong-jie ;
Ding, Dong ;
Liu, Meilin .
NANO ENERGY, 2014, 9 :161-167
[5]   Suppressing Manganese Dissolution in Potassium Manganate with Rich Oxygen Defects Engaged High-Energy-Density and Durable Aqueous Zinc-Ion Battery [J].
Fang, Guozhao ;
Zhu, Chuyu ;
Chen, Minghui ;
Zhou, Jiang ;
Tang, Boya ;
Cao, Xinxin ;
Zheng, Xusheng ;
Pan, Anqiang ;
Liang, Shuquan .
ADVANCED FUNCTIONAL MATERIALS, 2019, 29 (15)
[6]   Recent Advances in Aqueous Zinc-Ion Batteries [J].
Fang, Guozhao ;
Zhou, Jiang ;
Pan, Anqiang ;
Liang, Shuquan .
ACS ENERGY LETTERS, 2018, 3 (10) :2480-2501
[7]   Flexible Batteries: From Mechanics to Devices [J].
Fu, Kun Kelvin ;
Cheng, Jian ;
Li, Teng ;
Hu, Liangbing .
ACS ENERGY LETTERS, 2016, 1 (05) :1065-1079
[8]   A comparison study on Raman scattering properties of α- and β-MnO2 [J].
Gao, Tao ;
Fjellvag, Helmer ;
Norby, Poul .
ANALYTICA CHIMICA ACTA, 2009, 648 (02) :235-239
[9]   H+-Insertion Boosted α-MnO2 for an Aqueous Zn-Ion Battery [J].
Gao, Xu ;
Wu, Hanwen ;
Li, Wenjie ;
Tian, Ye ;
Zhang, Yun ;
Wu, Hao ;
Yang, Li ;
Zou, Guoqiang ;
Hou, Hongshuai ;
Ji, Xiaobo .
SMALL, 2020, 16 (05)
[10]   A three-dimensional interconnected V6O13 nest with a V5+-rich state for ultrahigh Zn ion storage [J].
He, Pingge ;
Liu, Jiahao ;
Zhao, Xudong ;
Ding, Zhengping ;
Gao, Peng ;
Fan, Li-Zhen .
JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (20) :10370-10376