Simultaneous detection of epinephrine, uric acid, and ascorbic acid with graphene-modified electrode

被引:9
作者
Chen, M. F. [1 ]
Ma, X. Y. [1 ]
机构
[1] Heze Univ, Dept Chem & Chem Engn, Heze 274015, Peoples R China
关键词
SELF-ASSEMBLED MONOLAYERS; GLASSY-CARBON ELECTRODE; GOLD NANOPARTICLES; SENSOR;
D O I
10.1134/S107042721402013X
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A graphene-modified glassy carbon electrode was obtained via drop-casting method and applied to the simultaneous detection of epinephrine, uric acid, and ascorbic acid by cyclic voltammetry in a phosphate buffer solution (pH 3.0). The oxidation potentials of epinephrine, uric acid, and ascorbic acid were 0.484, 0.650, and 0.184 V at the graphene-modified glassy carbon electrode, respectively. The peak separation between epinephrine Pand uric acid, epinephrine and ascorbic acid, and uric acid and ascorbic acid was about 166, 300, and 466 mV, respectively. So, this graphene-modified electrode can be used for simultaneous determination of each component in a mixture.
引用
收藏
页码:200 / 206
页数:7
相关论文
共 22 条
[1]   Hydrazine chemical sensing by modified electrode based on in situ electrochemically synthesized polyaniline/graphene composite thin film [J].
Ameen, Sadia ;
Akhtar, M. Shaheer ;
Shin, Hyung Shik .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 173 :177-183
[2]   A novel sensor of cysteine self-assembled monolayers over gold nanoparticles for the selective determination of epinephrine in presence of sodium dodecyl sulfate [J].
Atta, Nada F. ;
Galal, Ahmed ;
El-Ads, Ekram H. .
ANALYST, 2012, 137 (11) :2658-2668
[3]  
Bouhouti H.E., 2009, TALANTA, V79, P22
[4]   Electromechanical resonators from graphene sheets [J].
Bunch, J. Scott ;
van der Zande, Arend M. ;
Verbridge, Scott S. ;
Frank, Ian W. ;
Tanenbaum, David M. ;
Parpia, Jeevak M. ;
Craighead, Harold G. ;
McEuen, Paul L. .
SCIENCE, 2007, 315 (5811) :490-493
[5]   Electrochemical determination of isoprenaline using a graphene-modified glassy carbon electrode [J].
Chen, Meifeng ;
Ma, Xinying ;
Li, Xia .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2012, 16 (10) :3261-3266
[6]  
Deftereoss TN, 1993, ANALYST, V118, P627
[7]   Simultaneous determination of ascorbic acid, epinephrine, and uric acid by differential pulse voltammetry using poly(3,3′-bis[N,N-bis(carboxymethyl)aminomethyl]-o-cresolsulfonephthalein) modified glassy carbon electrode [J].
Ensafi, Ali A. ;
Rezaei, B. ;
Zare, S. Z. Mirahmadi ;
Taei, M. .
SENSORS AND ACTUATORS B-CHEMICAL, 2010, 150 (01) :321-329
[8]   A chemical route to graphene for device applications [J].
Gilje, Scott ;
Han, Song ;
Wang, Minsheng ;
Wang, Kang L. ;
Kaner, Richard B. .
NANO LETTERS, 2007, 7 (11) :3394-3398
[9]   Materials science - Graphene-based materials [J].
Li, Dan ;
Kaner, Richard B. .
SCIENCE, 2008, 320 (5880) :1170-1171
[10]   Alcohol intake, serum uric acid concentrations, and risk of gout [J].
Liberopoulos, EN ;
Miltiodous, GA ;
Elisaf, MS .
LANCET, 2004, 364 (9430) :246-247