Peculiarities of NMR spectra of heterospin complexes

被引：14
|
作者：
Sagdeev, RZ
Voronov, VK
Podoplelov, AV
Ushakov, IA
Chemezov, AN
Fursova, EY
Fokin, SV
Romanenko, GV
Reznikov, VA
Ovcharenko, VI
机构：
[1] Russian Acad Sci, Siberian Branch, Int Tomog Ctr, Novosibirsk 630090, Russia
[2] Irkutsk State Tech Univ, Irkutsk 664074, Russia
[3] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 11期
关键词：
NMR spectroscopy; nickel; chelate complexes; nitroxides; conformation equilibrium;
D O I：
10.1023/A:1015036915105
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Experimental investigation and theoretical simulation of the unusual phenomenon of multiple broadening and narrowing of NMR signals due to the temperature variation of a solution of the stereochemically non-rigid heterospin Ni2+ complex with stable nitroxide were performed. The investigation of the temperature dependence of the NMR signals of stereochemically non-rigid heterospin systems can be used for choosing conditions for growing heterospin single crystals containing molecules in a definite conformation.
引用
收藏
页码：2078 / 2086
页数：9
相关论文
共 50 条
  • [1] Peculiarities of NMR spectra of heterospin complexes
    R. Z. Sagdeev
    V. K. Voronov
    A. V. Podoplelov
    I. A. Ushakov
    A. N. Chemezov
    E. Y. Fursova
    S. V. Fokin
    G. V. Romanenko
    V. A. Reznikov
    V. I. Ovcharenko
    Russian Chemical Bulletin, 2001, 50 : 2078 - 2086
  • [2] The heterospin cobalt complexes: peculiarities of high-resolution NMR spectra
    Voronov, V. K.
    Ushakov, I. A.
    Funtikova, E. A.
    HELIYON, 2022, 8 (04)
  • [3] PECULIARITIES OF NMR MOLECULE SPECTRA IN HETEROGENEOUS SYSTEMS
    MANK, VV
    UKRAINSKII KHIMICHESKII ZHURNAL, 1978, 44 (09): : 911 - 918
  • [4] Structural peculiarities of phase transitions in heterospin systems
    Romanenko, G
    Fokin, S
    Ikorskii, V
    Ovcharenko, V
    JOURNAL DE PHYSIQUE IV, 2004, 114 : 643 - 644
  • [5] A New Method for the Synthesis of Heterospin Complexes
    Ovcharenko, Victor
    Kuznetsova, Olga
    Fursova, Elena
    Romanenko, Galina
    Bogomyakov, Artem
    CRYSTALS, 2015, 5 (04): : 634 - 649
  • [6] Heterospin complexes based on cobalt semiquinolate with nitroxides
    E. Yu. Fursova
    O. V. Kuznetsova
    E. V. Tretyakov
    G. V. Romanenko
    A. S. Bogomyakov
    V. I. Ovcharenko
    R. Z. Sagdeev
    V. K. Cherkasov
    M. P. Bubnov
    G. A. Abakumov
    Russian Chemical Bulletin, 2011, 60 : 809 - 815
  • [7] NMR spectra of indolizines and their sigma-complexes
    Babaev, EV
    Torocheshnikov, VN
    Bobrovsky, SI
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1995, (09): : 1235 - 1244
  • [8] NMR SPECTRA OF CARBENE COMPLEXES OF PLATINUM(II)
    BADLEY, EM
    KILBY, BJL
    RICHARDS, RL
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 27 (02) : C37 - &
  • [9] Heterospin complexes based on cobalt semiquinolate with nitroxides
    Fursova, E. Yu
    Kuznetsova, O. V.
    Tretyakov, E. V.
    Romanenko, G. V.
    Bogomyakov, A. S.
    Ovcharenko, V. I.
    Sagdeev, R. Z.
    Cherkasov, V. K.
    Bubnov, M. P.
    Abakumov, G. A.
    RUSSIAN CHEMICAL BULLETIN, 2011, 60 (05) : 809 - 815
  • [10] SOME PECULIARITIES OF MANY-IMPULSE NMR-SPECTRA IN CRYSTALLINE HYDRATES
    EROFEEV, LN
    KARNAUKH, GE
    SOSIKOV, AI
    FIZIKA TVERDOGO TELA, 1982, 24 (02): : 581 - 583
12345